Journal of the Chemical Society, Dalton Transactions: Volume 4 (2004)

Issue: 1

• Happy New Year from Dalton Transactions! (pp. E1-E2)
• The profound influence of a single metal–carbon bond on the reactivity of bio-relevant cobalt(iii) complexesPresented at the Inorganic Reaction Mechanism Discussion Group Meeting, Newcastle, UK, January 2003. (pp. 1-12) Hamza, Mohamed S. A.; Eldik, Rudi van
• Unusual photophysical switching in a Ru(ii) diimine DNA probe caused by amide functionalisation (pp. 13-15) O'Donoghue, Karen A.; Kelly, John M.; Kruger, Paul E.
• Identification of a novel high affinity copper binding site in the APP(145–155) fragment of amyloid precursor protein (pp. 16-22) Valensin, Daniela; Mancini, Francesca Maria; Łuczkowski, Marek; Janicka, Anna; Wiśniewska, Kornelia; Gaggelli, Elena; Valensin, Gianni; Łankiewicz, Leszek; Kozlowski, Henryk
• Charge density analysis of two polymorphs of antimony(iii) oxide (pp. 23-29) Whitten, Andrew E.; Dittrich, Birger; Spackman, Mark A.; Turner, Peter; Brown, Trevor C.
• Photosensitized generation of singlet oxygen from ruthenium(ii) and osmium(ii) bipyridyl complexes (pp. 30-36) Abdel-Shafi, Ayman A.; Worrall, David R.; Ershov, Aleksei Y.
• Dicatechol-diimines: easily accessible ligands for the self-assembly of dinuclear triple-stranded helicates (pp. 37-43) Albrecht, Markus; Janser, Ingo; Kamptmann, Susanne; Weis, Patrick; Wibbeling, Birgit; Fröhlich, Roland
• Synthesis, characterization and molecular structures of six-coordinate manganese nitrosyl porphyrinsElectronic supplementary information (ESI) available: Molecular structure of (TTP)Mn(NO)(1-MeIm). See http://www.rsc.org/suppdata/dt/b3/b308143p/ (pp. 44-50) Zahran, Zaki N.; Lee, Jonghyuk; Alguindigue, Susan S.; Khan, Masood A.; Richter-Addo, George B.
• Synthesis and properties of new ditertiary stibines based upon o-, m- or p-xylyl and m- or p-phenylene backbones and their complexes with tungsten, iron and nickel carbonyls (pp. 51-58) Levason, William; Matthews, Melissa L.; Reid, Gillian; Webster, Michael
• Antisymmetric exchange in two tricopper(ii) complexes containing a [Cu3(μ3-OMe)]5+ core (pp. 59-64) Liu, Xiaoming; de Miranda, Marcelo P.; McInnes, Eric J. L.; Kilner, Colin A.; Halcrow, Malcolm A.
• A study of the thermal and light induced spin transition in [FeL2](BF4)2 and [FeL2](ClO4)2 L = 2,6-di(3-methylpyrazol-1-yl)pyrazine (pp. 65-69) Money, Victoria A.; Elhaïk, Jerome; Radosavljevic Evans, Ivana; Halcrow, Malcolm A.; Howard, Judith A. K.
• Structural and NMR investigations of the ternary adducts of twenty α-amino acids and selected dipeptides with a chiral, diaqua–ytterbium complex (pp. 70-80) Dickins, Rachel S.; Batsanov, Andrei S.; Howard, Judith A. K.; Parker, David; Puschmann, Horst; Salamano, Stefania
• Effect of chelating vs. bridging coordination of chiral short-bite P–X–P (X = C, N, O) ligands in enantioselective palladium-catalysed allylic substitution reactionsElectronic supplementary information (ESI) available: Colour versions of Fig. 2 and Fig. 4. See http://www.rsc.org/suppdata/dt/b3/b309385a/ (pp. 81-89) Calabrò, GianPiero; Drommi, Dario; Bruno, Giuseppe; Faraone, Felice
• Synthesis and deprotonation of P–H-functionalised phosph(iii)azanes; borohydride dependency on the formation of cis- or trans-[HP(μ-NtBu)2PNtBuH] (pp. 90-93) Woods, Anthony D.; McPartlin, Mary
• Stability and kinetics of the acid-promoted decomposition of Cu(ii) complexes with hexaazacyclophanes: kinetic studies as a probe to detect changes in the coordination mode of the macrocyclesElectronic supplementary information (ESI) available: Table S1: Observed rate constants for the decomposition of the different Cu(ii) complexes with ligands L1–L6. Fig. S1: Spectral changes recorded during the decomposition of the H2CuL4+ (a) and HCuL3+ (b) complexes of L2 in the presence of 0.01 M HNO3. See http://www.rsc.org/suppdata/dt/b3/b311772c/ (pp. 94-103) Aguilar, Juan; Basallote, Manuel G.; Gil, Laura; Hernández, Juan C.; Máñez, M. Angeles; García-España, Enrique; Soriano, Conxa; Verdejo, Begoña
• A spectroscopic investigation of the interaction between nitrogen monoxide and copper sites of the fungal laccase from Rigidoporus lignosus (pp. 104-112) Bonomo, R. P.; Castronovo, B. M. G.; Santoro, A. M.
• Syntheses, structural properties and catecholase activity of copper(ii) complexes with reduced Schiff base N-(2-hydroxybenzyl)-amino acidsElectronic supplementary information (ESI) available: Thermogravimetry curves, UV/vis spectra, a plot of 1/ν vs. 1/[S], structure diagrams, plots of χ and μeff, and H-bond distances. See http://www.rsc.org/suppdata/dt/b3/b310262a/ (pp. 113-121) Yang, Chang-Tong; Vetrichelvan, Muthalagu; Yang, Xiandong; Moubaraki, Boujemaa; Murray, Keith S.; Vittal, Jagadese J.
• Metal ion recognition via ‘selective detuning’. The interaction of selected transition and post-transition metal ions with a mono-N-benzylated O2N3-donor macrocycle and its xylyl-bridged ring analogue (pp. 122-128) Fainerman-Melnikova, Marina; Nezhadali, Azizollah; Rounaghi, Gholamhossin; McMurtrie, John C.; Kim, Jeong; Gloe, Karsten; Langer, Matthias; Lee, Shim Sung; Lindoy, Leonard F.; Nishimura, Tomoko; Park, Ki-Min; Seo, Joobeom
• Cerium(iii) dialkyl dithiocarbamates from [Ce{N(SiMe3)2}3] and tetraalkylthiuram disulfides, and [Ce(κ2-S2CNEt2)4] from the CeIII precursor; TbIII and NdIII analogues (pp. 129-136) Hitchcock, Peter B.; Hulkes, Alexander G.; Lappert, Michael F.; Li, Zhengning
• Preparative and structural studies on iron(ii)–thiolate cyanocarbonyls: relevance to the [NiFe]/[Fe]-hydrogenases (pp. 137-143) Chen, Chien-Hong; Chang, Yung-Su; Yang, Chien-Yeh; Chen, Tai-Nan; Lee, Chien-Ming; Liaw, Wen-Feng
• Syntheses, structures and properties of 1-ethyl-3-methylimidazolium salts of fluorocomplex anionsElectronic supplementary information (ESI) available: Raman and IR assignments. See http://www.rsc.org/suppdata/dt/b3/b310162b/ (pp. 144-149) MatsumotoResearch Fellow of Japan Society for the Promotion of Science., Kazuhiko; Hagiwara, Rika; Yoshida, Ryuhei; Ito, Yasuhiko; Mazej, Zoran; Benkič, Primož; Žemva, Boris; Tamada, Osamu; Yoshino, Hideaki; Matsubara, Seijiro
• Preparation and photochemistry of cobalt(iii) amino and amino acidato complexes containing tripodal polypyridine ligandsElectronic supplementary information (ESI) available: Synthetic, spectroscopic and crystallographic details. See http://www.rsc.org/suppdata/dt/b3/b311809f/ (pp. 150-156) Otter, Carl A.; Hartshorn, Richard M.
• Preparation and NMR studies of cobalt-containing diphosphine ligand chelated W, Ru, Au and Pd complexes: Suzuki cross-coupling reactions and carbonylation catalyzed by the Pd complex (pp. 157-165) Hong, Fung-E; Chang, Yu-Chang; Chang, Chin-Pei; Huang, Yi-Luen
• Ligand discrimination in the reaction of nitrones with [PtCl2(PhCN)2]. Selective formation of mono-oxadiazoline and mixed bis-oxadiazoline complexes under thermal and microwave conditions (pp. 166-171) Desai, Bimbisar; Danks, Timothy N.; Wagner, Gabriele
• Zinc(ii) complexes with intramolecular amide oxygen coordination as models of metalloamidases (pp. 172-177) Rivas, Juan C. Mareque; Salvagni, Emiliano; Prabaharan, Ravi; de Rosales, Rafael Torres Martín; Parsons, Simon
• Coordination chemistry of 2-(8-aminoquinolino)-4,6-di-tert-butylphenol with manganese(iv), iron(iii), and cobalt(ii/iii):N,O-coordinated o-iminobenzosemiquinonate(1−) π radical monoanions vs. o-iminophenolate(2−) dianions (pp. 178-186) Sik Min, Kil; Weyhermüller, Thomas; Wieghardt, Karl

Issue: 2

• A manganese superoxide dismutase mimic based on cis,cis-1,3,5-triaminocyclohexaneElectronic supplementary information (ESI) available: Synthetic details, determination of the physical properties of ligands, SOD assays, electrochemistry and references. See http://www.rsc.org/suppdata/dt/b3/b314955b/ (pp. 187-188) Lewis, Elizabeth A.; Khodr, Hicham H.; Hider, Robert C.; Lindsay Smith, John R.; Walton, Paul H.
• Synthesis and molecular structures of nitrosoarene metalloporphyrin complexes of ruthenium (pp. 189-196) Lee, Jonghyuk; Twamley, Brendan; Richter-Addo, George B.
• Gas phase ion chemistry of charged silver(i) adenine ions via multistage mass spectrometry experiments and DFT calculationsGas phase ion chemistry of biomolecules, Part 38. For part 37, see ref. 1.Electronic supplementary information available: Tables (energies and bond lengths) and figures (MS spectra and optimised structures). See http://www.rsc.org/suppdata/dt/b3/b311656e/ (pp. 197-208) Vrkic, Ana K.; Taverner, Thomas; James, Patrick F.; O'Hair, Richard A. J.
• Generation of AuPd22/Au2Pd21 analogues of the high-nuclearity Pd23(CO)20(PEt3)10 cluster containing 19-atom centered hexacapped-cuboctahedral (ν2-octahedral) metal fragment: structural-to-synthesis approach concerning formation of Au2Pd21(CO)20(PEt3)10Dedicated by L. F. D. to Du Shriver on the occasion of his 69th birthday in remembrance of his remarkable professional career for over 40 years at Northwestern University as an exceptional researcher, especially in organometallic and metal cluster chemistry, and as a leading educator in modern inorganic chemistry. (pp. 209-216) Tran, Nguyet T.; Powell, Douglas R.; Dahl, Lawrence F.
• Nanosized Au2Pd41(CO)27(PEt3)15 containing two geometrically unprecedented 13-coordinated Au-centered (μ13-Au)Pd13 polyhedra connected by triangular face-sharing and three interpenetrating 12-coordinated Pd-centered (μ12-Pd)Au2Pd10 icosahedra: geometrical change in centered polyhedra induced by Au/Pd electronegativity-mismatchDedicated by L. F. D. to Fred Basalo on the occasion of his 83rd birthday in recognition of his highly illustrious scientific career in Inorganic Chemistry at Northwestern University and his tremendous impact as a researcher, educator, scholar, and inspirational leader. (pp. 217-223) Tran, Nguyet T.; PowellPresent address: University of Kansas (Lawrence, KS)., Douglas R.; Dahl, Lawrence F.
• Structural and magnetic properties of vanadyl dichloride solvates: from molecular units to extended hydrogen-bonded solids (pp. 224-228) Papoutsakis, Dimitris; Ichimura, Andrew S.; Young, Jr., Victor G.; Jackson, James E.; Nocera, Daniel G.
• Steric complementarity in carboxylate anion recognition (pp. 229-235) Nelson, Jane; Nieuwenhuyzen, Mark; Pál, Ibolya; Town, Raewyn M.
• A crystallographic, EPR and theoretical study of the Jahn–Teller distortion in [CuTp2] (Tp− = tris{pyrazol-1-yl}hydridoborate) (pp. 236-243) Kilner, Colin A.; McInnes, Eric J. L.; Leech, Michael A.; Beddard, Godfrey S.; Howard, Judith A. K.; Mabbs, Frank E.; Collison, David; Bridgeman, Adam J.; Halcrow, Malcolm A.
• Solvent extraction and lanthanide complexation studies with new terdentate ligands containing two 1,3,5-triazine moieties (pp. 244-251) Drew, Michael G. B.; Hill, Clement; Hudson, Michael J.; Iveson, Peter B.; Madic, Charles; Youngs, Tristan G. A.
• Different supramolecular hydrogen bond structures and significant changes in magnetic properties in dinuclear μ2-1,1-N3 copper(ii) complexes with very similar tridentate Schiff base blocking ligandsElectronic supplementary information (ESI) available: Figs. S1 and S2: ORTEP-3 views of complexes 2 and 3. Fig. S3: Representation of J values vs. Cu–N–Cu angles in asymmetric (basal–apical) geometries. Fig. S4: Simulation of χMT vs. T (for a ring of 12 copper(ii) ions, representing an infinite chain). See http://www.rsc.org/suppdata/dt/b3/b311499f/ (pp. 252-259) Ray, Mau Sinha; Ghosh, Ashutosh; Bhattacharya, R.; Mukhopadhyay, G.; Drew, M. G. B.; Ribas, Joan
• Synthesis, structural analysis, and magnetic behaviour of three fumarate bridged coordination polymers: five-fold interpenetrated diamond-like net of NiII, sheets of NiII and CoIIElectronic supplementary information (ESI) available: Selected bond lengths and angles for complexes 1–3. See http://www.rsc.org/suppdata/dt/b3/b311988b/ (pp. 260-266) Konar, Sanjit; Zangrando, Ennio; Drew, Michael G. B.; Ribas, Joan; Ray Chaudhuri, Nirmalendu
• Sulfite induced autoxidation of Ni(ii) and Co(ii) tetraglycine complexes. Spectrophotometric and rotating ring-disc voltammetric studies (pp. 267-272) Alipázaga, María V.; Lowinsohn, Denise; Bertotti, Mauro; Coichev, Nina
• Synthesis, X-ray structure, polarized optical spectra and DFT theoretical calculations of two new organic–inorganic hybrid fluoromanganates(iii): (bpaH2)[MnF4(H2O)2]2 and (bpeH2)[MnF4(H2O)2]2Electronic supplementary information (ESI) available: Further calculations to verify the true minimum of the calculated structure of [MnF4(H2O)2]. See http://www.rsc.org/suppdata/dt/b3/b311688c/ (pp. 273-278) Núñez, Pedro; Ruiz-Morales, Juan C.; Lozano-Gorrín, A. D.; Gili, Pedro; Rodriguez, Vicente D.; González-Platas, J.; Barriuso, Teresa; Rodríguez, Fernando
• Substitution reactions of [Pt(terpy)X]2+ with some biologically relevant ligands. Synthesis and crystal structure of [Pt(terpy)(cyst-S)](ClO4)2·0.5H2O and [Pt(terpy)(guo-N7)](ClO4)2·0.5guo·1.5H2OElectronic supplementary information (ESI) available: Observed pseudo-first order rate constants, kobs, as a function of ligand concentration and temperature (Figs. S1–3) and pressure (Fig. S4). Tables S1–11: Observed pseudo-first-order rate constants. Tables S12–16: Pressure dependences. See http://www.rsc.org/suppdata/dt/b3/b311056g/ (pp. 279-286) Bugarčić, Živadin D.; Heinemann, Frank W.; Eldik, Rudi van
• Electronically and sterically tuned trans labilization controls the substitution behaviour of cobaloximes (pp. 287-291) Hamza, Mohamed S. A.; Felluga, Alessandro; Randaccio, Lucio; Tauzher, Giovanni; van Eldik, Rudi
• Mechanistic information on the copper-catalysed autoxidation of mercaptosuccinic acid in aqueous solutionElectronic supplementary information (ESI) available: Spectral changes during reaction. See http://www.rsc.org/suppdata/dt/b3/b311053b/ (pp. 292-298) Pawelec, Marek; Stochel, Grażyna; van Eldik, Rudi
• Role of chelate substituents and cis σ-effect on the rate of ligand substitution at Pt(N–N–N) and Pt(N–N–C) centresElectronic supplementary information (ESI) available: A summary of the selected wavelengths used in the kinetic measurements, all measured rate constants and all the representative plots. See http://www.rsc.org/suppdata/dt/b3/b311595j/ (pp. 299-304) Jaganyi, D.; Reddy, D.; Gertenbach, J. A.; Hofmann, A.; van Eldik, R.
• Two-electron reduction of alkyl(sulfanyl)porphyrazines: a route to free-base and peripherally metallated asymmetric porphyrazinesElectronic supplementary information (ESI) available: 13C NMR spectra of H2OOSPz, H2HOSPz, H2HOSPz(Br) and [H2OOSPz]PtCl2, MALDI-MS and IR spectra of [H2OOSPz]PtCl2. See http://www.rsc.org/suppdata/dt/b3/b312495a/ (pp. 305-312) Belviso, Sandra; Giugliano, Anna; Amati, Mario; Ricciardi, Giampaolo; Lelj, Francesco; Monsù Scolaro, Luigi
• Zwitterionic macrocyclic metal sulfate extractants containing 3-dialkylaminomethylsalicylaldimine units (pp. 313-318) Plieger, Paul G.; Tasker, Peter A.; Galbraith, Stuart G.
• Metallation effects on the thermal interconversion of atropisomers of di(orthomethylarene)-substituted porphyrins (pp. 319-326) Plieger, Paul G.; Burrell, Anthony K.; Jameson, Geoffrey B.; Officer, David L.
• A paradigm shift in the construction of heterobimetallic complexes: Synthesis of group 2 & 4 metal–calix[6]arene complexes (pp. 327-333) Petrella, Antonella J.; Craig, Donald C.; Lamb, Robert N.; Raston, Colin L.; Roberts, Nicholas K.
• Electronic properties of Ru(ii) complexes bound to a bisphenolate bridge with low lying π* orbitalsElectronic supplementary information (ESI) available: Raman spectrum of solid BHD ligand excited at 514 nm. See http://www.rsc.org/suppdata/dt/b3/b312641b/ (pp. 334-341) Brady, Ian; Leane, Deirdre; Hughes, Helen P.; Forster, Robert J.; Keyes, Tia E.
• Complex formation reaction of the iron(iii) hydroxo dimer with periodate ionElectronic supplementary information (ESI) available: Figs. S1–6: 127I NMR spectra, UV-vis spectra, pH–potentiometric measurements and initial rate method plot. Raw kinetic data. See http://www.rsc.org/suppdata/dt/b3/b313341a/ (pp. 342-346) Kerezsi, Ildikó; Lente, Gábor; Fábián, István

Issue: 3

• What kinds of three-dimensional nets are possible with tris-chelated metal complexes as building blocks?Electronic supplementary information (ESI) available: Details of the CCDC search presented in Table 2; PDB-files with cartesian coordinates for the models shown in Fig. 3. See http://www.rsc.org/suppdata/dt/b3/b310330g/ (pp. 347-353) Öhrström, Lars; Larsson, Krister
• Hydrolysis of CpTiCl2(TEMPO) and its application on one-pot syntheses of CpTiCl(OR)2 complexes (pp. 354-356) Huang, Kuo-Wei; Waymouth, Robert M.
• Unexpected formation of a novel macrocyclic tetraphosphine: (RSSR)-1,9-dibenzyl-3,7,11,15-tetramesityl-1,9-diaza-3,7,11,15-tetraphosphacyclohexadecane (pp. 357-358) Naumov, Roman N.; Karasik, Andrey A.; Sinyashin, Oleg G.; Lönnecke, Peter; Hey-Hawkins, Evamarie
• Synthesis and catalytic activity of binuclear titanium imido complexes (pp. 359-360) Said, Musa; Hughes, David L.; Bochmann, Manfred
• The first example of a Si-bridged tris(pyridyl) ligand; synthesis and structure of [MeSi(2-C5H4N)3LiX] (X = 0.2Br, 0.8Cl) (pp. 361-362) García, Felipe; Hopkins, Alexander D.; Humphrey, Simon M.; McPartlin, Mary; Rogers, Michael C.; Wright, Dominic S.
• NMR and EPR structural delineation of copper(ii) complexes formed by kanamycin A in waterElectronic supplementary information (ESI) available: Table S1: 1H chemical shifts of KanA at different pH values; Table S2: Rnsel, Rsel, Rbsel, σ and τR of H2 protons of KanA at different pH values; Table S3: EPR magnetic parameters of Cu(ii)–KanA complexes at pH 7.4 and 12.0. Fig. S1: 1H NMR spectrum of KanA at 298 K and pH 5.5. See http://www.rsc.org/suppdata/dt/b3/b313060f/ (pp. 363-368) D′Amelio, Nicola; Gaggelli, Elena; Gaggelli, Nicola; Molteni, Elena; Baratto, Maria Camilla; Valensin, Gianni; Jezowska-Bojczuk, Malgorzata; Szczepanik, Wojciech
• Synthesis and characterisation of cyanodithioimidocarbonate [C2N2S2]2− complexes (pp. 369-374) Burchell, Colin J.; Aucott, Stephen M.; Milton, Heather L.; Slawin, Alexandra M. Z.; Derek Woollins, J.
• Vinyl and carbene ruthenium(ii) complexes from hydridoruthenium(ii) precursorsElectronic supplementary information (ESI) available: 1H and 13C NMR data for 5–24, 26, 27, 30 and 31. See http://www.rsc.org/suppdata/dt/b3/b314425a/Dedicated to Professor Jose Vicente, a respected scientist and friend, on the occasion of his 60th birthday. (pp. 375-383) Jung, Stefan; Brandt, Carsten D.; Wolf, Justin; Werner, Helmut
• Dynamic interaction of theory and experiment: total determination of the gas-phase molecular structure of tri-tert-butylphosphine oxide (OPBut3)Electronic supplementary information (ESI) available: Interatomic distances (r/pm) and amplitudes of vibration (u/pm) for the SARACEN (Table S1) and DYNAMITE (Table S4) GED structures of OPBut3. Least squares correlation matrix (×100) for the SARACEN (Table S2) and DYNAMITE (Table S5) GED refinements of OPBut3. Experimental gas electron diffraction coordinates from the SARACEN (Table S3) and DYNAMITE (Table S6) refinements of OPBut3. Table S7: Calculated parameters for the C3v molecular structure of OPMe3 at the HF/6-31G*, MP2/6-31G* and MP2/6-311G* levels. See http://www.rsc.org/suppdata/dt/b3/b313451b/ (pp. 384-391) Hinchley, Sarah L.; Haddow, Mairi F.; Rankin, David W. H.
• Synthesis and characterization of two novel mixed metal tellurates: KGaTeO5·H2O and K3GaTe2O8(OH)2·H2OElectronic supplementary information (ESI) available: Powder X-ray diffraction patterns for Na+- and Rb+-exchanged KGaTeO5·H2O. See http://www.rsc.org/suppdata/dt/b3/b312519j/ (pp. 392-396) Yu, Ranbo; Min Ok, Kang; Shiv Halasyamani, P.
• Different modes of aggregation in organoaluminium and -gallium hydroxylamides (pp. 397-401) Mitzel, Norbert W.; Lustig, Christian; Woski, Markus
• Diastereoselective synthesis of coordination compounds: a chiral tripodal ligand based on bipyridine units and its ruthenium(ii) and iron(ii) complexes (pp. 402-406) Hamann, Christine; von Zelewsky, Alexander; Neels, Antonia; Stoeckli-Evans, Helen
• Redox state switching of transition metals by deprotonation of the tridentate ligand 2,6-bis(imidazol-2-yl)pyridineElectronic supplementary information (ESI) available: Fig. S1: ORTEP view of the [Mn(1)2]2+ solvated complex. Fig. S2: ORTEP view of the [Mn(1)2]2+ non-solvated complex. Fig. S3: ORTEP view of the [Co(1 − 2H)2]− complex. See http://www.rsc.org/suppdata/dt/b3/b313440g/ (pp. 407-412) Stupka, Gilles; Gremaud, Ludovic; Bernardinelli, Gérald; Williams, Alan F.
• Preparation and characterisation of palladium, platinum and manganese di(organo)carbene complexes from quinolinone and quinolinium precursorsElectronic supplementary information (ESI) available: Fig. S1: Unit cell diagram of 5. Table S1: 1H and 13C-{1H} NMR data of ligand precursors 1a and 2. See http://www.rsc.org/suppdata/dt/b3/b314217p/ (pp. 413-420) Meyer, Wolfgang H.; Deetlefs, Maggel; Pohlmann, Michael; Scholz, Roland; Esterhuysen, Matthias W.; Julius, Gerrit R.; Raubenheimer, Helgard G.
• Speciation in the aqueous H+/H2VO4−/H2O2/picolinate system relevant to diabetes researchSpeciation in vanadium bioinorganic systems. Part 11. For part 10, see ref. 13.Electronic supplementary information (ESI) available: 51V NMR spectra and distributions of V species. See http://www.rsc.org/suppdata/dt/b3/b313424e/ (pp. 421-428) Andersson, Ingegärd; Gorzsás, András; Pettersson, Lage
• Kinetics and mechanism of water substitution in the low-spin Fe(ii) complex of 4-octasulfophenylpyrazinoporphyrazineElectronic supplementary information (ESI) available: A total of ten figures including 1H NMR spectra, kinetic traces, Eyring plots and plots of kobs as a function of pressure. See http://www.rsc.org/suppdata/dt/b3/b311695f/ (pp. 429-435) Kudrik, Evgeny V.; van Eldik, Rudi; Makarov, Sergei V.
• Synthesis of mono-amino-functionalised ferrocene, ferrocene salts and ferrocenium saltsElectronic supplementary information (ESI) available: Selected interatomic distances (Å) and selected angles between interatomic vectors (°) with estimated standard deviations in parentheses for compound 5. See http://www.rsc.org/suppdata/dt/b3/b315359m/ (pp. 436-441) Furtado, Stephen J.; Gott, Andrew L.; McGowan, Patrick C.
• Self-assembly of novel macrocyclic aminomethylphosphines with hydrophobic intramolecular cavities (pp. 442-447) Balueva, Anna S.; Kuznetsov, Roman M.; Ignat'eva, Svetlana N.; Karasik, Andrey A.; Gubaidullin, Aidar T.; Litvinov, Igor A.; Sinyashin, Oleg G.; Lönnecke, Peter; Hey-Hawkins, Evamarie
• Dichlorobis(2-phenylazopyridine)ruthenium(ii) complexes: characterisation, spectroscopic and structural properties of four isomersElectronic supplementary information (ESI) available: Pluton packing plots of the left-handed helices present in the crystals of γ-Cl; NOESY spectrum of α-Cl in acetone-d6. See http://www.rsc.org/suppdata/dt/b3/b313182c/ (pp. 448-455) Velders, Aldrik H.; van der Schilden, Karlijn; Hotze, Anna C. G.; Reedijk, Jan; Kooijman, Huub; Spek, Anthony L.
• Preparation, electrochemical and spectral properties of N-methylated pyridylethynyl porphyrinsElectronic supplementary information (ESI) available: Spectral changes of Zn0, Zn1, Zn3 and Zn5 reductions and the suggested mechanisms of Zn0–Zn6 reductions. See http://www.rsc.org/suppdata/dt/b3/b313575f/ (pp. 456-462) Lin, Ching-Yao; Chuang, Li-Chieh; Yang, Ya-Fen; Lin, Chun-Ling; Kao, Hsien-Chang; Wang, Wen-Jwu
• Coordination features of ditopic oxa-azamacrocycles toward Ni(ii) and Co(ii). Dioxygen uptake by their dinuclear Co(ii) complexesElectronic supplementary information (ESI) available: Stability constants of the Ni(ii) and Co(ii) mononuclear complexes with L1, L2 and L3. Crystal packing of [Ni2(L1)Br2(H2O)4]Br2·2H2O. See http://www.rsc.org/suppdata/dt/b3/b312751f/ (pp. 463-469) Bazzicalupi, Carla; Bencini, Andrea; Bianchi, Antonio; Duce, Celia; Fornasari, Patrizia; Giorgi, Claudia; Paoletti, Piero; Pardini, Rodolfo; Rosaria Tinè, Maria; Valtancoli, Barbara
• The reaction of GeCl4 with primary and secondary phosphines (pp. 470-475) Apostolico, Leonardo; Mahon, Mary F.; Molloy, Kieran C.; Binions, Russell; Blackman, Christopher S.; Carmalt, Claire J.; Parkin, Ivan P.
• Oxygen-17 NMR study of aqueous peroxotungstates (pp. 476-481) Howarth, Oliver W.
• Mono- and dinuclear molybdenum complexes with sterically demanding cycloheptatrienyl ligands (pp. 482-491) Tamm, Matthias; Bannenberg, Thomas; Fröhlich, Roland; Grimme, Stefan; Gerenkamp, Mareike
• Crystal structures of dicarboxy-2,2′-bipyridyl complexes: the role of hydrogen bonding and stacking interactionsElectronic supplementary information (ESI) available: Tables S1–S3: Hydrogen bonding parameters for [Rh(1H)3]·6H2O, [Ru(1H)2(1H2)]·2.5H2O and [Co(2H)3]·6H2O: See http://www.rsc.org/suppdata/dt/b3/b314539e/ (pp. 492-497) Matthews, Craig J.; Elsegood, Mark R. J.; Bernardinelli, Gérald; Clegg, William; Williams, Alan F.

Issue: 4

• Synthesis and P–P cleavage reactions of [P(X)X′]2; X-ray structures of [Co{P(X)X′}(CO)3] and P4[P(X)X′]2 [X = N(SiMe3)2, X′ = NPri2] (pp. 499-501) Bezombes, Jean-Philippe; Hitchcock, Peter B.; Lappert, Michael F.; Nycz, Jacek E.
• Self-assembly of molecular squares based on easy-to-prepare multidentate Schiff base ligands (pp. 502-504) He, Zheng; He, Cheng; Wang, Zhe-Ming; Gao, En-Qing; Liu, Yuan; Yan, Chun-Hua
• Robust hydrogen-bonded self-assemblies from biimidazole complexes. Synthesis and structural characterization of [M(biimidazole)2(OH2)2]2+ (M = Co2+, Ni2+) complexes and carboxylate modulesElectronic supplementary information (ESI) available: TG/DSC analyses for compound 4. See http://www.rsc.org/suppdata/dt/b3/b312541f/ (pp. 505-513) Atencio, Reinaldo; Chacón, Mirbel; González, Teresa; Briceño, Alexander; Agrifoglio, Giuseppe; Sierraalta, Anibal
• Synthesis and characterisation of ruthenium complexes containing a pendent catechol ringElectronic supplementary information (ESI) available: Fig. S1: molecular structure of [Ru(phen)2(L1)]+ showing atomic numbering; Fig. S2: pH dependence of the emission spectra of [Ru(phen)2(L2)]+; Table S1: energy and % contribution of atomic orbitals to each molecular orbital in the frontier region for (a) [Ru(bipy)2(L1)]+ and (b) [Ru(bipy)2(HL1)]2+. See http://www.rsc.org/suppdata/dt/b3/b311989k/ (pp. 514-522) O'Brien, Luke; Duati, Marco; Rau, Sven; Guckian, Adrian L.; Keyes, Tia E.; O'Boyle, Noel M.; Serr, Andreas; Görls, Helmar; Vos, Johannes G.
• 9,10-Anthracene dicarboxylate bridged complexes with M2 quadruply bonded dimetal units: [{M2(O2CtBu)3}2(μ-9,10-An(CO2)2)], where M = Mo or W (pp. 523-529) Byrnes, Matthew J.; Chisholm, Malcolm H.; Dye, David F.; Hadad, Christopher M.; Pate, Brian D.; Wilson, Paul J.; Zaleski, Jeffrey M.
• Synthesis and structure of the incomplete cuboidal clusters [W3Se4H3(dmpe)3]+, [W3Se4H3−x(OH)x(dmpe)3]+ and [W3Se4(OH)3(dmpe)3]+, and the mechanism of the acid-assisted substitution of the coordinated hydrides (pp. 530-536) Basallote, Manuel G.; Estevan, Francisco; Feliz, Marta; Jesús Fernández-Trujillo, M.; Hoyos, Dora A.; Llusar, Rosa; Uriel, Santiago; Vicent, Cristian
• Structural diversity in the coordination of amidines and guanidines to monovalent metal halides (pp. 537-546) Oakley, Sarah H.; Soria, Delia B.; Coles, Martyn P.; Hitchcock, Peter B.
• Stereoselective ligand-exchange reaction of planar-chiral cyclopentadienyl–ruthenium complexes: thermodynamic control of configuration at a stereogenic metal center (pp. 547-553) Matsushima, Yuji; Onitsuka, Kiyotaka; Takahashi, Shigetoshi
• Synthesis and characterisation of transition metal halide complexes of the xylyl-distibine, 1,2-bis(dimethylstibanylmethyl)benzene (pp. 554-561) Levason, William; Matthews, Melissa L.; Reid, Gillian; Webster, Michael
• Polymeric silver(i) complexes with pyridyl dithioether ligands: experimental and theoretical investigations on the coordination properties of the ligandsElectronic supplementary information (ESI) available: ESI-MS spectra. See http://www.rsc.org/suppdata/dt/b3/b315320g/ (pp. 562-569) Xie, Ya-Bo; Zhang, Chong; Li, Jian-Rong; Bu, Xian-He
• Magnesium and zinc complexes of a potentially tridentate β-diketiminate ligand (pp. 570-578) Dove, Andrew P.; Gibson, Vernon C.; Marshall, Edward L.; White, Andrew J. P.; Williams, David J.
• Lanthanide(iii)/actinide(iii) differentiation in coordination of azine molecules to tris(cyclopentadienyl) complexes of cerium and uranium (pp. 579-590) Mehdoui, Thouraya; Berthet, Jean-Claude; Thuéry, Pierre; Ephritikhine, Michel
• Protonation and coordination properties towards Zn(ii), Cd(ii) and Hg(ii) of a phenanthroline-containing macrocycle with an ethylamino pendant arm (pp. 591-597) Bazzicalupi, Carla; Bencini, Andrea; Berni, Emanuela; Bianchi, Antonio; Borsari, Lucia; Giorgi, Claudia; Valtancoli, Barbara; Lodeiro, Carlos; Lima, João Carlos; Parola, A. Jorge; Pina, Fernando
• The coordination chemistry of the hydrotris(3-diphenylmethylpyrazol-1-yl)borate (TpCHPh2) ligand (pp. 598-604) Rheingold, Arnold L.; Liable-Sands, Louise M.; Golen, James A.; Yap, Glenn P. A.; Trofimenko, Swiatoslaw
• Dinuclear Zn2+ complexes in the hydrolysis of the phosphodiester linkage in a diribonucleoside monophosphate diesterElectronic supplementary information (ESI) available: Fig. S1 – 1H NMR spectra of the Zn(NO3)2 + 3 mixtures; Fig. S2 – titration data and theoretical curves; Fig. 3S – molecular models of Zn21H−2 and Zn22H−1. See http://www.rsc.org/suppdata/dt/b3/b312301d/ (pp. 605-610) Yashiro, Morio; Kaneiwa, Hideki; Onaka, Kenichi; Komiyama, Makoto
• Anionic carbonato and oxalato cobalt(iii) nitrogen mustard complexesElectronic supplementary information (ESI) available: Table of hydrogen bonds for 6b and 8. See http://www.rsc.org/suppdata/dt/b3/b311091e/ (pp. 611-618) Craig, Peter R.; Brothers, Penelope J.; Clark, George R.; Wilson, William R.; Denny, William A.; Ware, David C.
• Organoplatinum(iv) tris-chelate complexes, each having a cyclic metallacarbonate ring: synthesis, characterization and kinetic studies of the formation (pp. 619-622) Rashidi, Mehdi; Shahabadi, Nahid; Masoud Nabavizadeh, S.
• Cross-couplings in the elaboration of luminescent bis-terpyridyl iridium complexes: the effect of extended or inhibited conjugation on emission (pp. 623-631) Leslie, Wendy; Batsanov, Andrei S.; Howard, Judith A. K.; Gareth Williams, J. A.
• Rationalisation of weak ferromagnetism in manganese(iii) chains: the relation between structure and ordering phenomenaElectronic supplementary information (ESI) available: Fig. S1: View along the crystallographic b axis showing the pattern of weak hydrogen bonds connecting the manganese ions Mn and Mniii. Fig. S2: Zero-field cooled and field cooled temperature-dependent magnetisation of a powdered sample of 1 measured at 50 Oe. Fig. S3: Magnetisation and hysteresis at 2 K of a powdered sample of 1 measured as a function of the applied field by scanning down in field. Details of the calculation of the dipolar interaction. See http://www.rsc.org/suppdata/dt/b3/b314355d/ (pp. 632-639) Mossin, Susanne; Weihe, Høgni; Osholm Sørensen, Henning; Lima, Nicola; Sessoli, Roberta
• Design and coordination behavior of the first selective recognition ligand of 147Pm(iii)Electronic supplementary information (ESI) available: Table S1: Analytical data for the complexes (%). Table S2: Selected bond lengths (Å) and angles (°) for the complexes. See http://www.rsc.org/suppdata/dt/b3/b312381b/ (pp. 640-644) Liu, Weisheng; Li, Xiaofeng; Wen, Yonghong; Tan, Minyu
• Acid–base equilibria of various oxidation states of aqua–ruthenium complexes with 1,10-phenanthroline-5,6-dione in aqueous mediaElectronic supplementary information (ESI) available: 1H NMR spectrum of [1](ClO4)2 (Fig. S1), Cyclic voltammogram of [1](ClO4)2 (Fig. S2), pH dependent UV-vis spectra of [2](ClO4)2 (Fig. S3), and cyclic voltammograms of [2](ClO4)2 (Fig. S4). See http://www.rsc.org/suppdata/dt/b3/b312310c/ (pp. 645-652) Fujihara, Tetsuaki; Wada, Tohru; Tanaka, Koji
• The influence of the boat-to-chair conversion on the demetallation of the nickel(ii) complex of an open-chain tetramine containing a piperazine fragment (pp. 653-658) Boiocchi, Massimo; Bonizzoni, Marco; Fabbrizzi, Luigi; Foti, Francesco; Licchelli, Maurizio; Taglietti, Angelo; Zema, Michele
• Synthesis, structure and reactivity of ferrio-chloro-phosphanes, -arsanes and -stibanes [(CO)2(η5-C5Me5)FePn(Cl)R] (Pn = P, As, Sb); R = tetramethylcyclopentadienyl, 2,7-di-tert-butylfluorenyl, 2,7-di-tert-butyl-9-trimethylsilylfluorenyl) as precursor to novel metallo-phosphaalkenes, -arsaalkenes, and -stibaalkenes (pp. 659-667) Weber, Lothar; Pumpenmeier, Lars; Stammler, Hans-Georg; Neumann, Beate
• [Ru(TAP)2(dppz)]2+: a DNA intercalating complex, which luminesces strongly in water and undergoes photo-induced proton-coupled electron transfer with guanosine-5′-monophosphate (pp. 668-676) Ortmans, Isabelle; Elias, Benjamin; Kelly, John M.; Moucheron, Cécile; Kirsch-DeMesmaeker, Andrée
• Stable gold(iii) complexes with thiosemicarbazone derivativesElectronic supplementary information (ESI) available: Tables S1–4: Hydrogen bonds in the complexes [Au(Hdamp-C1)(L3b)]Cl2·3H2O, [Au(Hdamp-C1)(L3c)]Cl2·2H2O, [AuCl(L3a)]Cl·2MeOH, [AuCl(L3a)]Cl·2MeOH and [AuCl(L3b)]Cl·MeOH. Fig. S1: Molecular packing scheme in [AuCl(L3a)]Cl·2MeOH. See http://www.rsc.org/suppdata/dt/b3/b312978k/ (pp. 677-682) Garcia Santos, Isabel; Hagenbach, Adelheid; Abram, Ulrich
• Bi- and poly-metallic cyanide-bridged complexes of the redox-active cyanomanganese nitrosyl unit [Mn(CN)(PR3)(NO)(η-C5H4Me)] (pp. 683-694) Adams, Christopher J.; Anderson, Kirsty M.; Bardaji, Manuel; Connelly, Neil G.; Goodwin, Nicholas J.; Llamas-Rey, Estefania; Guy Orpen, A.; Rieger, Philip H.

Issue: 5

• Self-assembly sodalite-like frameworkElectronic supplementary information (ESI) available: Preparation, crystal structure determination and refinement details. See http://www.rsc.org/suppdata/dt/b3/b316981b/ (pp. 695-696) Solntsev, Pavlo V.; Sieler, Joachim; Chernega, Alexander N.; Howard, Judith A. K.; Gelbrich, Thomas; Domasevitch, Konstantin V.
• Intramolecular nucleophilic activation promoting efficient hydrolytic cleavage of DNA by (aqua)bis(dipyridoquinoxaline)copper(ii) complexElectronic supplementary information (ESI) available: Table S1. Comparison of rate values for hydrolytic cleavage of DNA by different metal complexes. See http://www.rsc.org/suppdata/dt/b4/b401383b/ (pp. 697-698) Dhar, Shanta; Reddy, Pattubala A. N.; Chakravarty, Akhil R.
• Complexes of 5,5′-aminoacido-substituted 2,2′-bipyridyl ligands: control of diastereoselectivity with a pH switch and a chloride-responsive combinatorial library (pp. 699-705) Telfer, Shane G.; Yang, Xiao-Juan; Williams, Alan F.
• Electrochemical and theoretical study of the redox properties of transition metal complexes with {Pt2S2} cores (pp. 706-712) Mas-Ballesté, Rubén; Capdevila, Mercé; González-Duarte, Pilar; Hamidi, Mohamed; Lledós, Agustí; Mégret, Claire; de MontauzonDominique de Montauzon passed away on August 13th, 2001., Dominique
• Synthesis, characterisation and molecular structure of Re(iii) 2-oxacyclocarbenes stabilised by a benzoyldiazenido ligand (pp. 713-722) Marvelli, Lorenza; Mantovani, Nicoletta; Marchi, Andrea; Rossi, Roberto; Brugnati, Michele; Peruzzini, Maurizio; Barbaro, Pierluigi; de los Rios, Isaac; Bertolasi, Valerio
• Tuning facial–meridional isomerisation in monometallic nine-co-ordinate lanthanide complexes with unsymmetrical tridentate ligandsElectronic supplementary information (ESI) available: Luminescence data for [Eu(L2)3]3+ and [Tb(L2)3]3+ (Table S1), elemental analyses (Table S2), structural data for the lanthanide co-ordination sphere in [Eu(L1)2(CF3SO3)2(H2O)](CF3SO3)(C3H5N)2(H2O) (6) and [Eu(L4)2(CF3SO3)2(H2O)](CF3SO3)(THF)1.5 (7) (Table S3); an optimised superimposition of the two molecular structures of [Eu(L5)3]3+ (X-ray and calculated in the gas phase, Fig. S1), perspective views of the molecular structures of fac-[Lu(L3)3]3+ and mer-[Lu(L3)3]3+ (Fig. S2) and fac-[Lu(L4)3]3+ and mer-[Lu(L4)3]3+ (Fig. S3) obtained by molecular mechanics in the gas-phase. See http://www.rsc.org/suppdata/dt/b3/b316035a/ (pp. 723-733) Le Borgne, Thierry; Altmann, Peter; André, Nicolas; Bünzli, Jean-Claude G.; Bernardinelli, Gérald; Morgantini, Pierre-Yves; Weber, Jacques; Piguet, Claude
• The structural and spectroscopic characterisation of three actinyl complexes with coordinated and uncoordinated perrhenate: [UO2(ReO4)2(TPPO)3], [{(UO2)(TPPO)3}2(µ2-O2)][ReO4]2 and [NpO2(TPPO)4][ReO4]Electronic supplementary information (ESI) available: Mid-infrared ATR and Raman spectra. See http://www.rsc.org/suppdata/dt/b3/b313045b/ (pp. 734-740) John, Gordon H.; May, Iain; Sarsfield, Mark J.; Steele, Helen M.; Collison, David; Helliwell, Madeleine; McKinney, James D.
• Thermodynamic and biodistribution studies of Zn(ii), Ca(ii), Gd(iii) and Cu(ii) complexes of 3,3,9,9-tetramethyl-4,8-diazaundecane-2,10-dione dioximeCopper anti-inflammatory drugs in rheumatoid arthritis. Part 6.1 (pp. 741-749) Nomkoko, Thembelani E.; Jackson, Graham E.; Nakani, Bandile S.; Louw, Werner K. A.; Zeevaart, Jan R.
• {(μ-L)[RuII(acac)2]2}n, n = 2+, +, 0, −, 2−, with L = 3,3′,4,4′-tetraimino-3,3′,4,4′-tetrahydrobiphenyl. EPR-supported assignment of NIR absorptions for the paramagnetic intermediatesElectronic supplementary information (ESI) available: 1H NMR (Fig. S1) and FAB-mass spectra (Fig. S2) for 1. See http://www.rsc.org/suppdata/dt/b3/b315927m/ (pp. 750-753) Patra, Srikanta; Sarkar, Biprajit; Ghumaan, Sandeep; Fiedler, Jan; Záliš, Stanislav; Kaim, Wolfgang; Kumar Lahiri, Goutam
• The triruthenium complex [{(acac)2RuII}3(L)] containing a conjugated diquinoxaline[2,3-a:2′,3′-c]phenazine (L) bridge and acetylacetonate (acac) as ancillary ligands. Synthesis, spectroelectrochemical and EPR investigation (pp. 754-758) Patra, Srikanta; Sarkar, Biprajit; Ghumaan, Sandeep; Fiedler, Jan; Kaim, Wolfgang; Lahiri, Goutam Kumar
• Molecular structure of 1,1,2,2-tetra-tert-butyldisilane: unusual structural motifs in sterically crowded disilanesElectronic supplementary information (ESI) available: Structural results from calculations at the HF level with the 3-21G* and 6-31G* basis sets (Table S1), geometric and amplitude restraints (Table S2), least-squares correlation matrix (Table S3), and experimental coordinates from the GED analysis (Table S4). See http://www.rsc.org/suppdata/dt/b3/b316701a/ (pp. 759-766) Hinchley, Sarah L.; Robertson, Heather E.; Parkin, Andrew; Rankin, David W. H.; Tekautz, Günther; Hassler, Karl
• Embracing ligands. Synthesis, characterisation and the correlation between 59Co NMR and ligand field parameters of Co(iii) complexes with a new class of nitrogen–thioether multidentate ligandElectronic supplementary information (ESI) available: Nafion film UV-visible absorption spectra of [Co(PrN4S2amp)]3+ at room temperature and 14 K. See http://www.rsc.org/suppdata/dt/b3/b313189k/ (pp. 767-777) Sharrad, Clint A.; Cavigliasso, Germán E.; Stranger, Robert; Gahan, Lawrence R.
• Novel one-dimensional structures and solution behaviour of copper(ii) bromide and chloride complexes of a new pentapyridyldiamine ligandElectronic supplementary information (ESI) available: Table S1: Selected bands from FTIR spectra of solid-state species in KBr disks. Table S2: UV-Vis-NIR spectroscopic data. Fig. S1: Views of the crystal structure of [Cu2(L)Br3]2[Cu2Br4], illustrating: (a) the chains of bromide-bridged [Cu2(L)Br2]2+ tectons and interspersed [Cu2Br4]2− counter ions; (b) the packing of the chains and [Cu2Br4]2− counter ions. See http://www.rsc.org/suppdata/dt/b3/b315202b/ (pp. 778-787) Lonnon, David G.; Craig, Donald C.; Colbran, Stephen B.; Bernhardt, Paul V.
• CpRu(CO)2(BF4) and [CpFe(CO)2(THF)]+ on mesoporous silica as adsorbents for the removal of dibenzothiophenes from hydrocarbon solutions (pp. 788-793) McKinley, Scott G.; Vecchi, Paul A.; Ellern, Arkady; Angelici, Robert J.
• Mixed-metal sandwich complexes [MII2(H2O)2FeIII2(P2W15O56)2]14− (MII = Co, Mn): Synthesis and stability. The molecular structure of [MII2(H2O)2FeIII2(P2W15O56)2]14−Dedicated to Prof. P. Gouzerh on the occasion of his 60th birthday. (pp. 794-800) Ruhlmann, Laurent; Canny, Jacqueline; Vaissermann, Jacqueline; Thouvenot, René
• A unique coordination environment for an ion: EXAFS studies and bond valence model approach of the encapsulated cation in the Preyssler anion (pp. 801-806) Chiang, Ming-Hsi; Antonio, Mark R.; Williams, Clayton W.; Soderholm, L.
• Steric control in the oligomerisation of phosphazane dimers; towards new phosphorus–nitrogen macrocycles (pp. 807-812) Doyle, Emma L.; García, Felipe; Humphrey, Simon M.; Kowenicki, Richard A.; Riera, Lucía; Woods, Anthony D.; Wright, Dominic S.
• Novel Cd(ii) coordination polymers with flexible disulfoxide ligands: effects of ligand spacers, terminal groups and counter anions on the complex framework formations (pp. 813-819) Li, Jian-Rong; Bu, Xian-He; Zhang, Ruo-Hua
• A severely interrupted germanate zeolite framework synthesised from isolated double four-ring unitsElectronic supplementary information (ESI) available: XRD and NMR data. See http://www.rsc.org/suppdata/dt/b3/b314942k/ (pp. 820-824) Villaescusa, Luis A.; Wheatley, Paul S.; Morris, Russell E.; Lightfoot, Philip
• Two complexes of Sm(ii) with crown ethers—electrochemical synthesis, structure and spectroscopy (pp. 825-832) Starynowicz, Przemysław
• QALE analysis of CO dissociative kinetics of Ru(CO)4L (L = P-donor ligands): accelerating effects of hydrogen in PHnR3 − n ligands (n = 1–2)Electronic supplementary information (ESI) available: Kinetic data. See http://www.rsc.org/suppdata/dt/b3/b315719a/ (pp. 833-838) Babij, Claudia; Chen, Lezhan; Koshevoy, Igor O.; Poë, Anthony J.
• Molecular and supramolecular features of oxo-peroxovanadium complexes containing O3N, O2N2 and ON3 donor setsElectronic supplementary information (ESI) available: Table S1: Overview of the preparation of compounds 1 to 7; Table S2: Structure details of the O=V (carboxylic acid/carboxylate) moieties in 1a and 1b; Scheme S1: Structure details of 21a[ClO4]·1b·2.25H2O. Additional experimental details: Syntheses of [nBu4]3, K[3]·H2O, alternative route to 6[ClO4], [6]Cl, and 7. See http://www.rsc.org/suppdata/dt/b3/b315291j/ (pp. 839-846) Časný, Marian; Rehder, Dieter

Issue: 6

• Aqueous solution chemistry of [Mo3CuSe4]n+ (n = 4, 5) and [W3CuQ4]5+ (Q = S, Se) clusters (pp. 847-851) Hernandez-Molina, Rita; Sokolov, Maxim; Esparza, Pedro; Vicent, Cristian; Llusar, Rosa
• The building block approach to extended solids: 3,5-pyrazoledicarboxylate coordination compounds of increasing dimensionality (pp. 852-861) King, Philippa; Clérac, Rodolphe; Anson, Christopher E.; Powell, Annie K.
• New pyridine carboxamide ligands and their complexation to copper(ii). X-Ray crystal structures of mono-, di, tri- and tetranuclear copper complexes (pp. 862-871) Jain, Sneh L.; Bhattacharyya, Pravat; Milton, Heather L.; Slawin, Alexandra M. Z.; Crayston, Joe A.; Woollins, J. Derek
• Substrate selectivity and conformational space available to bromoxynil and acrylonitrile in iron nitrile hydratase (pp. 872-877) Desai, Lopa V.; Zimmer, Marc
• Hydrophobic vitamin B12. Part 19:For Part 18 see ref. 22. Electroorganic reaction of DDT mediated by hydrophobic vitamin B12 (pp. 878-882) Shimakoshi, Hisashi; Tokunaga, Mami; Hisaeda, Yoshio
• Pyridylpyrrolides as alternatives to cyclometalated phenylpyridine ligands: synthesis and characterization of luminescent zinc and boron pyridylpyrrolide complexesElectronic supplementary information (ESI) available: Beer’s Law plots and emission peak area vs. concentration plots for complexes; comparison of excitation and absorbance spectra; effect of triplet quencher isoprene on luminescence intensity. See http://www.rsc.org/suppdata/dt/b3/b315523d/ (pp. 883-891) Klappa, Jamie J.; Geers, Sarah A.; Schmidtke, Sarah J.; MacManus-Spencer, Laura A.; McNeill, Kristopher
• Reactions of cationic iron clusters with ammonia, models of nitrogen hydrogenation and dehydrogenationElectronic supplementary information (ESI) available: Table S1: Cartesian coordinates (Å). See http://www.rsc.org/suppdata/dt/b3/b316600g/ (pp. 892-897) Fossan, Kjell O.; Uggerud, Einar
• Supramolecular triangular and linear arrays of metal–radical solids using pyrazolato-silver(i) motifs (pp. 898-903) Yamada, Susumu; Ishida, Takayuki; Nogami, Takashi
• Redistribution and fluxionality in heteropolyoxoperoxo complexes: [PO4{M2O2(μ-O2)2(O2)2}2]3− with M = Mo and/or W (pp. 904-907) Salles, Laurent; Thouvenot, René; Brégeault, Jean-Marie
• Mixed crystals containing the dioxo complex [{Ph3SiO}2VO2]− and novel pentacoordinated oxoperoxo complex [{Ph3SiO}2VO(O2)]−: X-ray crystal structure and assessment as oxidation catalysts (pp. 908-913) Vennat, Maxence; Brégeault, Jean-Marie; Herson, Patrick
• Electrochemical anion recognition with ferrocene functionalised macrocyclesElectronic supplementary information (ESI) available: Figs. S1–S8. See http://www.rsc.org/suppdata/dt/b4/b400538d/ (pp. 914-920) Bernhardt, Paul V.; Creevey, Nicole L.
• Synthesis, characterization and ethylene reactivity of 2-diphenylphosphanylbenzamido nickel complexes (pp. 921-928) Kwon, Heon Yong; Lee, Su Yeon; Lee, Bun Yeoul; Shin, Dong Mok; Chung, Young Keun
• Insertion reactions of SO2 into Pd–OR bonds: preparation of alkyl sulfito complexes of palladium(ii)Electronic supplementary information (ESI) available: Table S1: 1H and 19F NMR data. See http://www.rsc.org/suppdata/dt/b3/b316697j/ (pp. 929-932) Ruiz, José; Martínez, M. Teresa; Florenciano, Félix; Rodríguez, Venancio; López, Gregorio; Pérez, José; Chaloner, Penny A.; Hitchcock, Peter B.
• Generation and trapping reaction of an efficient 1,2-dehydrocarborane precursor, phenyl[o-(trimethylsilyl)carboranyl]iodonium acetate (pp. 933-937) Lee, Taegweon; Jeon, Joonsang; Song, Kyu Ho; Jung, Il; Baik, Chul; Park, Ki-Min; Lee, Shim Sung; Kang, Sang Ook; Ko, Jaejung
• Synthesis and structure of boron-bridged constrained geometry complexes of titanium (pp. 938-943) Braunschweig, Holger; Breitling, Frank M.; Koblinski, Carsten von; White, Andrew J. P.; Williams, David J.
• Novel lanthanide(ii) complexes supported by carbon-bridged biphenolate ligands: synthesis, structure and catalytic activity (pp. 944-950) Deng, Mingyu; Yao, Yingming; Shen, Qi; Zhang, Yong; Sun, Jin
• Gold derivatives of scorpionates: comparison with the other coinage metal poly(pyrazolyl)borate analogues (pp. 951-958) Gioia Lobbia, Giancarlo; Hanna, John V.; Pellei, Maura; Pettinari, Claudio; Santini, Carlo; Skelton, Brian W.; White, Allan H.
• Extending the coordination capabilities of tertiary phosphines and arsines: preparation, molecular structure, and reactivity of dinuclear rhodium complexes with PR3 and AsR3 in a doubly bridging coordination mode (pp. 959-966) Pechmann, Thomas; Brandt, Carsten D.; Werner, Helmut
• Molecular structure of Hf(BH4)4 investigated by quantum mechanical calculations and gas-phase electron diffraction (pp. 967-970) Borisenko, Konstantin B.; Downs, Anthony J.; Robertson, Heather E.; Rankin, David W. H.; Tang, Christina Y.

Issue: 7

• A centred, elongated ‘ferric tetrahedron’ with an S = 15/2 spin ground state (pp. 975-976) Tabernor, James; Jones, Leigh F.; Heath, Sarah L.; Muryn, Chris; Aromí, Guillem; Ribas, Joan; Brechin, Euan K.; Collison, David
• Selective formation of the [PhP(H)–PPh]− anion in the reaction of PhPHLi with MeAlCl2; synthesis and structure of the unusual tetramer [{PhP(H)–PPh}Li·thf]4 (pp. 977-979) García, Felipe; Humphrey, Simon M.; Kowenicki, Richard A.; McPartlin, Mary; Wright, Dominic S.
• Unusual structural trends in the [MCl3([8]aneSe2)] (M = As, Sb, Bi) adductsElectronic supplementary information (ESI) available: Table containing a comparison of selected bond lengths (Å) and angles (°) in [M2Cl8]2− and [MCl3([8]aneSe2)] (M = As, Sb, Bi). See http://www.rsc.org/suppdata/dt/b4/b401384k/ (pp. 980-981) Hill, Nicholas J.; Levason, William; Patel, Rina; Reid, Gillian; Webster, Michael
• Magnetic behavior and Mössbauer spectra of spin-crossover pyrazolate bridged dinuclear diiron(ii) complexes: X-ray structures of high-spin and low-spin [{Fe(NCBH3)(py)}2(μ-bpypz)2]Electronic supplementary information (ESI) available: Fig. S1: 1H NMR spectra for complexes 1 and 3. Fig. S2: Crystal structure of the low-temperature form of complex 2. Fig. S3: χmT vs. T data for complexes 5 (a) and 6 (b). See http://www.rsc.org/suppdata/dt/b3/b314211f/ (pp. 982-988) Nakano, Keisaku; Suemura, Naohiko; Kawata, Satoshi; Fuyuhiro, Akira; Yagi, Takashi; Nasu, Saburo; Morimoto, Syotaro; Kaizaki, Sumio
• From the tetra(amino) phosphonium cation, [P(NHPh)4]+, to the tetra(imino) phosphate trianion, [P(NPh)4]3−, two-faced ligands that bind anions and cations (pp. 989-995) Bickley, Jamie F.; Copsey, May C.; Jeffery, John C.; Leedham, Angela P.; Russell, Christopher A.; Stalke, Dietmar; Steiner, Alexander; Stey, Thomas; Zacchini, Stefano
• Characterisation of [Cu4S], the catalytic site in nitrous oxide reductase, by EPR spectroscopyElectronic supplementary information (ESI) available: Listings of the coordinates used for the calculations; comparison of the results from restricted and unrestricted DFT calculations; schematic structure of a model CuZ. See http://www.rsc.org/suppdata/dt/b3/b313913a/ (pp. 996-1002) Oganesyan, Vasily S.; Rasmussen, Tim; Fairhurst, Shirley; Thomson, Andrew J.
• Synthesis, structure and magnetism of new single molecule magnets composed of MnII2MnIII2 alkoxo-carboxylate bridged clusters capped by triethanolamine ligandsElectronic supplementary information (ESI) available: Detailed magnetisation discussion, Mn bond valence sums (Table S1), H-bonding details (Table S2). See http://www.rsc.org/suppdata/dt/b3/b312672b/ (pp. 1003-1011) Wittick, Lisa M.; Murray, Keith S.; Moubaraki, Boujemaa; Batten, Stuart R.; Spiccia, Leone; Berry, Kevin J.
• Alkene metatheses in transition metal coordination spheres: dimacrocyclizations that join trans positions of square-planar platinum complexes to give topologically novel diphosphine ligands (pp. 1012-1028) Shima, Takanori; Bauer, Eike B.; Hampel, Frank; Gladysz, J. A.
• Homolysis of the Ln–N (Ln = Yb, Eu) bond. Synthesis, structural characterization and catalytic activity of ytterbium(ii) and europium(ii) complexes with methoxyethyl functionalized indenyl ligands (pp. 1029-1037) Zhang, Kehua; Zhang, Wu; Wang, Shaowu; Sheng, Enhong; Yang, Gaosheng; Xie, Meihua; Zhou, Shuangliu; Feng, Yan; Mao, Lili; Huang, Zixiang
• Dinuclear gold(i) complexes of bridging bidentate carbene ligands: synthesis, structure and spectroscopic characterisationElectronic supplementary information (ESI) available: Fig. S1—unit cell contents for 3; Fig. S2—unit cell contents for 9. See http://www.rsc.org/suppdata/dt/b3/b316804b/ (pp. 1038-1047) Barnard, Peter J.; Baker, Murray V.; Berners-Price, Susan J.; Skelton, Brian W.; White, Allan H.
• Antiferromagnetic coupling between rare earth ions and semiquinones in a series of 1 ∶ 1 complexesElectronic supplementary information (ESI) available: plot of χT and ΔχT vs. T for Sm(iii) and Eu(iii) derivatives (Figs. S1 and S2). Plot of M vs. H curves of Dy(iii) derivatives at 2.5 K (Fig. S3). Plot of low-temperature X-band EPR spectrum of Dy(DTBSQ)(HBPz3)2 (Fig. S4). Plot of M vs. H curves of Er(iii) derivatives at 2.5 K (Fig. S5). See http://www.rsc.org/suppdata/dt/b4/b401144a/ (pp. 1048-1055) Caneschi, Andrea; Dei, Andrea; Gatteschi, Dante; Poussereau, Sandrine; Sorace, Lorenzo
• Kinetics and mechanism of the ferroxime(ii)-catalysed biomimetic oxidation of 2-aminophenol by dioxygen. A functional phenoxazinone synthase modelElectronic supplementary information (ESI) available: Table S1: Initial rates of dioxygen uptake as a function of catalyst, substrate and dioxygen concentration. See http://www.rsc.org/suppdata/dt/b3/b316543d/ (pp. 1056-1060) Simándi, Tatiana M.; Simándi, László I.; Győr, Miklós; Rockenbauer, Antal; Gömöry, Ágnes
• Visible absorption spectra of metal–catecholate and metal–tironate complexes (pp. 1061-1072) Sever, Mary J.; Wilker, Jonathan J.
• Synthesis, structural and magnetic properties of a series of copper(ii) complexes containing a monocarboxylated perchlorotriphenylmethyl radical as a coordinating open-shell ligand (pp. 1073-1082) Maspoch, D.; Ruiz-Molina, D.; Wurst, K.; Vidal-Gancedo, J.; Rovira, C.; Veciana, J.
• Yttrium complexes incorporating the chelating diamides {ArN(CH2)xNAr}2− (Ar = C6H3-2,6-iPr2, x = 2, 3) and their unusual reaction with phenylsilaneElectronic supplementary information (ESI) available: Molecular structure of [Y{ArN(CH2)3NAr}(OC6H3-2,6-tBu2-4-Me)(THF)], selected region of the variable-temperature 1H NMR spectrum of 6 in d8-toluene, tables of selected bond lengths (Å), angles (°), selected crystallographic data, full crystal data and structure refinements for 7–11 and 14–16, syntheses of YI3, potassium menthoxide, 4 and 10–13. See http://www.rsc.org/suppdata/dt/b4/b400149d/ (pp. 1083-1096) Avent, Anthony G.; Cloke, F. Geoffrey N.; Elvidge, Benjamin R.; Hitchcock, Peter B.
• Regioselective HON-addition of bifunctional hydrazone oximes to Pt(iv)-bound nitrilesDedicated to Professor Ilya I. Moiseev on the occasion of his 75th birthday. (pp. 1097-1103) Garnovskii, Dmitrii A.; Pombeiro, Armando J. L.; Haukka, Matti; Sobota, Piotr; Kukushkin, Vadim Yu.
• A study on oxygen insertion in dinuclear silver cryptates (pp. 1104-1111) Wang, Zhi-Lin; Luo, Qin-Hui; Duan, Chun-Ying; Shen, Cheng-Yu; Li, Yi-Zhi

Issue: 8

• Poly(guanidyl)silanes as a new class of chelating, N-based ligand (pp. 1113-1114) Oakley, Sarah H.; Coles, Martyn P.; Hitchcock, Peter B.
• A novel dinuclear cyclometalated iridium complex bridged with 1,4-bis[pyridine-2-yl]benzene: its structure and photophysical properties (pp. 1115-1116) Tsuboyama, Akira; Takiguchi, Takao; Okada, Shinjiro; Osawa, Masahisa; Hoshino, Mikio; Ueno, Kazunori
• PtCl(PHCy2){(PCy2O)2H}: a hydrogen bonded phosphinito complex obtained by direct reaction of molecular oxygen with a terminal phosphido complexElectronic supplementary information (ESI) available: Fig. S1: ESI-MS positive spectrum of 2. Fig. S2: 1H NMR spectrum of 2 in the low-field region. Fig. S3: 195Pt{1H} NMR spectrum of 2. Fig. S4: 2-D 1H/195Pt XHCOR NMR spectrum of 2. Fig. S5: IR spectrum of 2 (Nujol mull). Fig. S6: 31P{1H} NMR spectrum of 2. Fig. S7: J-resolved 1H NMR spots of 2. Table S1: Spectroscopic features of 3. See http://www.rsc.org/suppdata/dt/b4/b402180k/ (pp. 1117-1119) Mastrorilli, Piero; Latronico, Mario; Nobile, Cosimo Francesco; Suranna, Gian Paolo; Fanizzi, Francesco Paolo; Englert, Ulli; Ciccarella, Giuseppe
• Liquid crystals of silver complexes derived from simple 1-alkylimidazoles (pp. 1120-1126) Lee, Ching K.; Hsu, Kuang-Mei; Tsai, Chun-Hsien; Lai, Chung K.; Lin, Ivan J. B.
• Transition metal-directed self-assembly of calix[4]arene based dithiocarbamate ligands (pp. 1127-1135) Webber, Philip R. A.; Drew, Michael G. B.; Hibbert, Richard; Beer, Paul D.
• Structural and near-IR photophysical studies on ternary lanthanide complexes containing poly(pyrazolyl)borate and 1,3-diketonate ligandsElectronic supplementary information (ESI) available: Tables S1–8: coordination sphere bond lengths and angles of the remainder of the complexes; Fig. S1: Molecular structure of the complex cation of [Nd(L1)2][Nd(dbm)4]. See http://www.rsc.org/suppdata/dt/b4/b400992d/ (pp. 1136-1144) Davies, Graham M.; Aarons, Rebecca J.; Motson, Graham R.; Jeffery, John C.; Adams, Harry; Faulkner, Stephen; Ward, Michael D.
• DNA binding and biological activity of some platinum(ii) intercalating compounds containing methyl-substituted 1,10-phenanthrolinesElectronic supplementary information (ESI) available: Binding data determined for platinum complexes bound to calf thymus DNA, linear dicroism spectra, Absorption spectra of the DNA alone and of the platinum complexes with DNA and solubilities of complexes in water. See http://www.rsc.org/suppdata/dt/b3/b316511f/ (pp. 1145-1152) Brodie, Craig R.; Collins, J. Grant; Aldrich-Wright, Janice R.
• Fused pyridazines: rigid multidentates for designing and fine-tuning the structure of hybrid organic/inorganic frameworksElectronic supplementary information (ESI) available: crystal structure determination and refinement details for 1–8. See http://www.rsc.org/suppdata/dt/b3/b316561b/ (pp. 1153-1158) Solntsev, Pavlo V.; Sieler, Joachim; Krautscheid, Harald; Domasevitch, Konstantin V.
• Modulation of the metal recognition properties of a new type of azaferrocenophane-based chemosensors: co-ordination chemistry towards Mg2+, Ca2+, Zn2+ and Ni2+ (pp. 1159-1165) Tárraga, Alberto; Molina, Pedro; López, Juan L.; Velasco, María D.
• Synthesis, characterization and DFT studies of the cobalt(iii) complex of a tetrapodal pentadentate N4S donor ligand (pp. 1166-1172) Sharrad, Clint A.; Cavigliasso, Germán E.; Stranger, Robert; Gahan, Lawrence R.
• Anionic Fischer-type carbene complexes as bidentate (N,O) ligandsElectronic supplementary information (ESI) available: molecular structures of 4b, 5, 7 and 8. See http://www.rsc.org/suppdata/dt/b3/b316998g/ (pp. 1173-1180) Raubenheimer, Helgard G.; Toit, Aletta du; Toit, Maria du; An, Jin; Niekerk, Lizette van; Cronje, Stephanie; Esterhuysen, Catharine; Crouch, Andrew M.
• Synthesis and characterisation of cyclopentadienyl complexes of barium: precursors for atomic layer deposition of BaTiO3 (pp. 1181-1188) Hatanpää, Timo; Vehkamäki, Marko; Mutikainen, Ilpo; Kansikas, Jarno; Ritala, Mikko; Leskelä, Markku
• Recognition of phosphate monoester dianion by an alkoxide-bridged dinuclear zinc(ii) complex (pp. 1189-1193) Kinoshita, Eiji; Takahashi, Makoto; Takeda, Hironori; Shiro, Motoo; Koike, Tohru
• Hetero di- and trinuclear Cu–Gd complexes with trifluoroacetate bridges: synthesis, structural and magnetic studiesElectronic supplementary information (ESI) available: π–π assembled infinite ribbon in the crystal structure of 4; two-dimensional layers in the crystal structure of 2 and energy levels for 1, 3 and 4. See http://www.rsc.org/suppdata/dt/b3/b312186k/ (pp. 1194-1200) Novitchi, Ghenadie; Shova, Sergiu; Caneschi, Andrea; Costes, Jean-Pierre; Gdaniec, Maria; Stanica, Nicolae
• Synthesis, structure and comparison of the DNA cleavage ability of metal complexes M(ii)L with the N-(2-ethoxyethanol)-bis(2-picolyl)amine ligand L (M = Co, Ni, Cu and Zn) (pp. 1201-1207) Kirin, Srecko I.; Happel, Christoph M.; Hrubanova, Silvia; Weyhermüller, Thomas; Klein, Christoph; Metzler-Nolte, Nils
• Metallocorroles as sensing components for gas sensors: remarkable affinity and selectivity of cobalt(iii) corroles for CO vs. O2 and N2Electronic supplementary information (ESI) available: Adsorption isotherms of corroles 5 and 6, IR spectra of the corrole/CO species (corroles 3–5) (Figs. S1–S3). See http://www.rsc.org/suppdata/dt/b3/b316706b/ (pp. 1208-1214) Barbe, Jean-Michel; Canard, Gabriel; Brandès, Stéphane; JérômePresent address: LACCO-ESIP, UMR 6503 CNRS, Université de Poitiers, 40, Avenue du Recteur Pineau, 86022 Poitiers, France., François; DuboisPresent address: IBM Almaden Research Center, 650 Harry Road, San Jose, CA 95120, USA., Géraud; Guilard, Roger
• Strain-induced substitutional lability in a Ru(ii) complex of a hypodentate polypyridine ligand (pp. 1215-1220) Åkermark, Björn; Bjernemose, Jens; Börje, Anna; Chmielewski, Piotr J.; Paulsen, Hauke; Simonsen, Ole; Stein, Paul C.; Toftlund, Hans; Wolny, Juliusz A.
• Syntheses and structural systematics of trialkylphosphine complexes of open titanocenes, zirconocenes and hafnocenes (pp. 1221-1226) Harvey, Benjamin G.; Basta, Rehan; Arif, Atta M.; Ernst, Richard D.
• Photophysical properties of closely-coupled, binuclear ruthenium(ii) bis(2,2′:6′,2″-terpyridine) complexes (pp. 1227-1232) Benniston, Andrew C.; Grosshenny, Vincent; Harriman, Anthony; Ziessel, Raymond
• Effect of the parent ligand on the photophysical properties of closely-coupled, binuclear ruthenium(ii) tris(2,2′-bipyridine) complexes (pp. 1233-1238) Benniston, Andrew C.; Harriman, Anthony; Romero, Francisco M.; Ziessel, Raymond
• Reactions of lanthanoid metals with 3,5-diphenylpyrazole at elevated temperatures: synthesis and structures of both homoleptic, [Ln3(Ph2pz)9] (Ln = La, Nd), [Ln2(Ph2pz)6] (Ln = Er, Lu), and heteroleptic, [Ln(Ph2pz)3(Ph2pzH)2] (Ln = La, Nd, Gd, Tb, Er or Yb), pyrazolate complexesElectronic supplementary information (ESI) available: Tables S1–4: Detailed bond distance and angle data. See http://www.rsc.org/suppdata/dt/b4/b400541d/ (pp. 1239-1247) Deacon, Glen B.; Forsyth, Craig M.; Gitlits, Alex; Skelton, Brian W.; White, Allan H.
• Interaction of desferrioxamine B (DFB) model dihydroxamic acids with some essential and toxic metal(ii) ions: effects of the structure and length of connecting chains on the metal ion selectivityElectronic supplementary information (ESI) available: Fig. S1: 1H NMR and 13C–1H COSY NMR spectra recorded for 2,5-DIHA. Fig. S2: 1H NMR spectra recorded for (a) 3,4-DIHA and (b) Pb(ii)–3,4-DIHA as a function of pH at 1 ∶ 2 metal to ligand ratio. Fig. S3: Some UV-VIS spectra recorded for Cu(ii)–2,5-DIHA as a function of pH at 1 ∶ 2 metal to ligand ratio. Fig. S4: Some UV-VIS spectra recorded for Ni(ii)–2,2-DIHA as a function of pH at 1 ∶ 2 metal to ligand ratio. Fig. S5: Concentration distribution curves calculated for Pb(ii)–2,5-DIHA and Pb(ii)–2,2-DIHA at 1 ∶ 2 metal to ligand ratio. See http://www.rsc.org/suppdata/dt/b4/b401426j/ (pp. 1248-1253) Farkas, Etelka; Bátka, Dávid; Pataki, Zoltán; Buglyó, Péter; Santos, M. Amelia
• Reactivity of the dimesityl-1,8-naphthalenediylborate anion: isolation of the borataalkene isomer and synthesis of 1,8-diborylnaphthalenes (pp. 1254-1258) Hoefelmeyer, James D.; Solé, Stéphane; Gabbaï, François P.
• Template synthesis of {(MoV2O4)(O3PCH2PO3)}n clusters (n = 3, 4, 10): solid state and solution studies (pp. 1259-1263) Peloux, Charlotte du; Dolbecq, Anne; Mialane, Pierre; Marrot, Jérôme; Sécheresse, Francis
• Three-ring, branched cyclam derivatives and their interaction with nickel(ii), copper(ii), zinc(ii) and cadmium(ii)Electronic supplementary information (ESI) available: Fig. 1S: Spectrophotometric titration curve for the addition of nickel(ii) nitrate hexahydrate to 3. Fig. 2S: EPR spectra for the copper(ii) perchlorate complexes of (a) 1, (b) 2 and (c) 4. Fig. 3S: EPR spectrum for the copper(ii) perchlorate complex of 3. Figs 4S–6S: Cyclic voltammograms for [Ni(2)](ClO4)2, [Ni3(3)](ClO4)6 and [Ni3(4)](ClO4)6. See http://www.rsc.org/suppdata/dt/b4/b401254m/ (pp. 1264-1270) Dong, Ying; Lindoy, Leonard F.; Turner, Peter; Wei, Gang
• Molecular zinc phosphonates: synthesis and X-ray crystal structures of [{(ZnMe)4(THF)2}{tBuPO3}2] and [{(ZnEt)3(Zn(THF))3}{tBuPO3}4{μ3-OEt}] (pp. 1271-1275) Anantharaman, Ganapathi; Chandrasekhar, Vadapalli; Walawalkar, Mrinalini G.; Roesky, Herbert W.; Vidovic, Denis; Magull, Jörg; Noltemeyer, Mathias

Issue: 9

• Total enantioselectivity in the DNA binding of the dinuclear ruthenium(ii) complex [{Ru(Me2bpy)2}2(μ-bpm)]4+ {bpm = 2,2′-bipyrimidine; Me2bpy = 4,4′-dimethyl-2,2′-bipyridine} (pp. 1277-1283) Smith, Jayden A.; Collins, J. Grant; Patterson, Bradley T.; Keene, F. Richard
• The dimeric and tetrameric octarepeat fragments of prion protein behave differently to its monomeric unitElectronic supplementary information (ESI) available: Figs. a–e: Distribution profiles of free and complexed fractions of Cu2+ ions with ligands in competition studies. See http://www.rsc.org/suppdata/dt/b4/b402090a/ (pp. 1284-1293) Valensin, Daniela; Luczkowski, Marek; Mancini, Francesca Maria; Legowska, Anna; Gaggelli, Elena; Valensin, Gianni; Rolka, Krzysztof; Kozlowski, Henryk
• Preparation and topotactical oxidation of ScVO3 with bixbyte structure: a low-temperature route to stabilize the new defect fluorite ScVO3.5 metastable phase (pp. 1294-1297) Alonso, José Antonio; Casais, María Teresa.; Martínez-Lope, María Jesús
• New mixed alkaline-earth nitridomolybdate(vi) nitride oxides with anion-ordered sub-structuresDedicated to Dr Marten G. Barker in memoriam. (pp. 1298-1303) Baker, Charles F.; Barker, Marten G.; Wilson, Claire; Gregory, Duncan H.
• Nickel(ii), copper(ii) and zinc(ii) binding properties and cytotoxicity of tripodal, hexadentate tris(ethylenediamine) – analogue chelators (pp. 1304-1311) Ye, Neng; Park, Gyungse; Przyborowska, Ann M.; Sloan, Paula E.; Clifford, Thomas; Bauer, Cary B.; Broker, Grant A.; Rogers, Robin D.; Ma, Rong; Torti, Suzy V.; Brechbiel, Martin W.; Planalp, Roy P.
• The coordination chemistry of copper(i) in liquid ammonia, trialkyl and triphenyl phosphite, and tri-n-butylphosphine solutionElectronic supplementary information (ESI) available: Fig. S1: The complex distribution function for the copper(i)–ammonia system in water. Figs. S2–S11: Fits of the experimental EXAFS data and the individual contributions from the different scattering paths. See http://www.rsc.org/suppdata/dt/b4/b400888j/ (pp. 1312-1319) Nilsson, Kersti B.; Persson, Ingmar
• A new [2 + 1] mixed ligand concept based on [99(m)Tc(OH2)3(CO)3]+: a basic study (pp. 1320-1328) Mundwiler, Stefan; Kündig, Monika; Ortner, Kirstin; Alberto, Roger
• Unexpected formation of a copper(ii) 12-metallacrown-4 with (S)-glutamic-γ-hydroxamic acid: a thermodynamic and spectroscopic study in aqueous solution (pp. 1329-1333) Tegoni, Matteo; Dallavalle, Francesco; Belosi, Barbara; Remelli, Maurizio
• Quantum chemistry-based interpretations on the lowest triplet state of luminescent lanthanides complexes. Part 1. Relation between the triplet state energy of hydroxamate complexes and their luminescence properties (pp. 1334-1347) Gutierrez, Fabien; Tedeschi, Christine; Maron, Laurent; Daudey, Jean-Pierre; Poteau, Romuald; Azema, Joëlle; Tisnès, Pierre; Picard, Claude
• Solid-supported cross-coupling catalysts derived from homogeneous nickel and palladium coordination complexesElectronic supplementary information (ESI) available: Synthesis of the complexes and crystallographic data for 1 and 2. See http://www.rsc.org/suppdata/dt/b3/b316553c/ (pp. 1348-1357) Phan, Nam T. S.; Brown, David H.; Adams, Harry; Spey, Sharon E.; Styring, Peter
• Mixed nitrogen/oxygen ligand affinities for bipositive metal ions and dioxygen binding to cobalt(ii) complexes (pp. 1358-1365) Del Piero, Silvia; Melchior, Andrea; Polese, Pierluigi; Portanova, Roberto; Tolazzi, Marilena
• Cationic Rh complexes with novel spiro tetraarylpentaborate anions prepared from arylboronic acids and aryloxorhodium complexes (pp. 1366-1375) Nishihara, Yasushi; Nara, Kyoko; Nishide, Yasuhiro; Osakada, Kohtaro
• Cation sensors containing a (bpy)Re(CO)3 group linked to an azacrown ether via an alkenyl or alkynyl spacer: synthesis, characterisation, and complexation with metal cations in solution (pp. 1376-1385) Lewis, Jared D.; Moore, John N.
• Synthesis and solid state characterisation of mononuclear 2-benzoylpyridine N-methyl-N-phenylhydrazone palladium(ii) complexes (pp. 1386-1392) Ghedini, Mauro; Aiello, Iolinda; Crispini, Alessandra; Deda, Massimo La
• Peroxomolybdate(vi)–citrate and –malate complex interconversions by pH-dependence. Synthetic, structural and spectroscopic studiesElectronic supplementary information (ESI) available: UV-Vis, IR spectra, TG and DSC analyses. See http://www.rsc.org/suppdata/dt/b3/b315280d/Dedicated to Prof. Khi-Rui Tsai on the occasion of his 90th birthday. (pp. 1393-1399) Zhou, Zhao-Hui; Hou, Shu-Ya; Wan, Hui-Lin
• Anionic triazine systemsDedicated to Professor Dr G.-V. Röschenthaler on the occasion of his 60th birthday. (pp. 1400-1404) Kingston, Melanie; Chen, Shan-Jia; Lork, Enno; Mews, Rüdiger
• Pyrene-sensitised near-IR luminescence from ytterbium and neodymium complexesElectronic supplementary information (ESI) available: Fitted time resolved profiles for the metal centred luminescence from the complexes. See http://www.rsc.org/suppdata/dt/b4/b401302f/ (pp. 1405-1409) Faulkner, Stephen; Carrié, Marie-Christine; Pope, Simon J. A.; Squire, Jonathan; Beeby, Andrew; Sammes, Peter G.
• Aminoacid N-substituted 1,4,7-triazacyclononane and 1,4,7,10-tetraazacyclododecane Zn2+, Cd2+ and Cu2+ complexes. A preparative, potentiometric titration and NMR spectroscopic studyElectronic supplementary information (ESI) available: Titration curve for H333+ alone and in the presence of Zn2+, Cd2+ and Cu2+. Fig. S2: Distribution variation of 3 and derived species with pH in the presence of Zn2+. See http://www.rsc.org/suppdata/dt/b4/b401763c/ (pp. 1410-1417) Plush, Sally E.; Lincoln, Stephen F.; Wainwright, Kevin P.
• An iron(ii) dihydrogen hydrido complex containing the tripodal tetraphosphine ligand P(CH2CH2PMe2)3 (pp. 1418-1423) Field, Leslie D.; Li, Hsiu L.; Messerle, Barbara A.; Smernik, Ronald J.; Turner, Peter
• Solution dynamics and molecular structure elucidation of novel aluminium derivatives containing diaminodimethylsilane ligandsElectronic supplementary information (ESI) available: Table ESI1: Selection of kinetic parameters. Fig. ESI1: Eyring plots. See http://www.rsc.org/suppdata/dt/b4/b400661e/ (pp. 1424-1431) Passarelli, Vincenzo; Benetollo, Franco; Zanella, Pierino
• In vitro and in vivo stability investigations of Cu(ii), Zn(ii), Ca(ii) and Gd(iii) complexes with N,N′-bis(2-hydroxyiminopropionyl) propane-1,3-diamineCopper anti‐inflammatory drugs in rheumatoid arthritis. Part 7.1 (pp. 1432-1440) Nomkoko, Edmund T.; Jackson, Graham E.; Nakani, Bandile S.
• Steric control of lanthanide hydration state: fast water exchange at gadolinium in a mono-amide ‘DOTA’ complex (pp. 1441-1445) Congreve, Aileen; Parker, David; Gianolio, Eliana; Botta, Mauro
• Self-assembled polynuclear clusters derived from some flexible polydentate dihydrazide ligands (pp. 1446-1455) Zhao, Liang; Niel, Virginie; Thompson, Laurence K.; Xu, Zhiqiang; Milway, Victoria A.; Harvey, Rosemary G.; Miller, David O.; Wilson, Claire; Leech, Michael; Howard, Judith A. K.; Heath, Sarah L.
• Electron paramagnetic resonance studies on copper(ii)–cyclodextrin systems (pp. 1456-1460) Fragoso, Alex; Camilla Baratto, Maria; Díaz, Alicia; Rodríguez, Yan; Pogni, Rebecca; Basosi, Riccardo; Cao, Roberto
• The reduction of tris-dithiolene complexes of molybdenum(vi) and tungsten(vi) by hydroxide ion: kinetics and mechanism (pp. 1461-1465) Cervilla, Antonio; Pérez-Plá, Francisco; Llopis, Elisa; Piles, María
• Cleavage of the peptide bond of β-alanyl-l-histidine (carnosine) induced by a CoIII–amine complexes: reaction, structure and mechanism (pp. 1466-1473) Saha, Manas K.; Mukhopadhyay, Uday; Bernal, Ivan
• Unique example of flexible phenol coordination in mononuclear manganese compounds (pp. 1474-1480) Reddig, Nicole; Pursche, Daniel; Rompel, Annette
• Arene–ruthenium complexes with salicyloxazolines: diastereoselective synthesis, configurational stability and applications as asymmetric catalysts for Diels–Alder reactions (pp. 1481-1492) Davenport, Adam J.; Davies, David L.; Fawcett, John; Russell, David R.
• Reversible and selective amine interactions of [Cd(μ2-N,O-p-NH2C6H4SO3)2(H2O)2]nElectronic supplementary information (ESI) available: Fig. S1: IR spectra of [Cd(μ2-N,O-p-NH2C6H4SO3)2(H2O)2]n (1) and the amine adducts (2–8). Fig. S2: The reaction vessel containing the C3H7NH2 adduct 4, showing the wet crystals. Table S1: elemental analysis results. See http://www.rsc.org/suppdata/dt/b4/b400790p/ (pp. 1493-1497) Zhou, Jin-Sen; Cai, Jiwen; Wang, Li; Ng, Seik-Weng

Issue: 10

• Heteroscorpionate ligands based on bis(pyrazol-1-yl)methane: design and coordination chemistry (pp. 1499-1510) Otero, A.; Fernández-Baeza, J.; Antiñolo, A.; Tejeda, J.; Lara-Sánchez, A.
• Structural, magnetic and DFT studies of a hydroxide-bridged {Cr8} wheel (pp. 1511-1512) Christian, Paul; Rajaraman, Gopalan; Harrison, Andrew; McDouall, Joseph J. W.; Raftery, James T.; Winpenny, Richard E. P.
• Synthesis and characterisation of macrocyclic palladium(ii)–sodium(i) complexes: generation of an unusual metal-mediated electron delocalisationElectronic supplementary information (ESI) available: Synthetic procedures for 1; molecular structure of [BaLH2(ClO4)2]; partial COSY-NMR spectra of 2 and 3; molecular structures of 2 and 3; packing structure of 3; and comparison of UV-visible spectra of 2 and 3. See http://www.rsc.org/suppdata/dt/b4/b402507e/ (pp. 1513-1515) Yoon, Il; Goto, Midori; Shimizu, Toshimi; Lee, Shim Sung; Asakawa, Masumi
• The thermal and light induced spin transition in [FeL2](BF4)2 (L = 2,6-dipyrazol-1-yl-4-hydroxymethylpyridine) (pp. 1516-1518) Money, V. A.; Elhaïk, J.; Halcrow, M. A.; Howard, J. A. K.
• Well-defined indium(iii) N-heterocyclic carbene complexes with triflate ligands: Structural models for the In(OTf)3 catalystElectronic supplementary information (ESI) available: Full experimental data for the new compounds. See http://www.rsc.org/suppdata/dt/b4/b404179h/ (pp. 1519-1520) Cotgreave, Jamie H.; Colclough, David; Kociok-Köhn, Gabriele; Ruggiero, Giuseppe; Frost, Christopher G.; Weller, Andrew S.
• Macropolyhedral boron-containing cluster chemistry. Ligand-induced two-electron variations of intercluster bonding intimacy. Structures of nineteen-vertex [(η5-C5Me5)HIrB18H19(PMe2Ph)] and the related carbene complex [(η5-C5Me5)HIrB18H19{C(NHMe)2}] (pp. 1521-1523) Shea, Suzanne L.; Jelínek, Tomáš; Perera, Sarath D.; Štíbr, Bohumil; Thornton-Pett, Mark; Kennedy, John D.
• Photoinduced Ru–Yb energy transfer and sensitised near-IR luminescence in a coordination polymer containing co-crystallised [Ru(bipy)(CN)4]2− and Yb(iii) units (pp. 1524-1526) Miller, Thomas A.; Jeffery, John C.; Ward, Michael D.; Adams, Harry; Pope, Simon J. A.; Faulkner, Stephen
• Solid state coordination chemistry: structural consequences of variations in tether length in the oxovanadium–copper–bisterpy–{O3P(CH2)nPO3}4− system, n = 1–6 (bisterpy = 2,2′:4′,4″:2″,2‴-quarterpyridyl-6′,6″-di-2-pyridine) (pp. 1527-1538) Ouellette, Wayne; Koo, Bon-Kweon; Burkholder, Eric; Golub, Vladimir; O'Connor, C. J.; Zubieta, Jon
• Nickel and iron complexes with oxazoline- or pyridine-phosphonite ligands; synthesis, structure and application for the catalytic oligomerisation of ethyleneDedicated to Prof. F. Sécheresse on the occasion of his 60th birthday. (pp. 1539-1545) Speiser, Fredy; Braunstein, Pierre; Saussine, Lucien
• Binding sites on the outside of metallo-supramolecular architectures; engineering coordination polymers from discrete architecturesElectronic supplementary information (ESI) available: Fig. S1: View showing the herringbone style packing of the π-stacked columns in the structure of ligand La. See http://www.rsc.org/suppdata/dt/b4/b403749a/ (pp. 1546-1555) Pascu, Mirela; Tuna, Floriana; Kolodziejczyk, Edyta; Pascu, Gabriel I.; Clarkson, Guy; Hannon, Michael J.
• Theoretical study of reaction pathways for the rhodium phosphine-catalysed borylation of C–H bonds with pinacolboraneElectronic supplementary information (ESI) available: Figs. S1–S5: Selected structural parameters calculated for the reactive species discussed in the text. Cartesian coordinates of optimised structures. See http://www.rsc.org/suppdata/dt/b4/b402632b/ (pp. 1556-1562) Lam, Wai Han; Lam, King Chung; Lin, Zhenyang; Shimada, Shigeru; Perutz, Robin N.; Marder, Todd B.
• Mononucleotide recognition by cyclic trinuclear palladium(ii) complexes containing 4,7-phenanthroline N,N bridgesElectronic supplementary information (ESI) available: ORTEP view of the [((S,S)-dach)Pd(4,7-phen)]36+ cations in the crystal structure of 2b. Experimental details of the partial crystal structure solution of 2b. See http://www.rsc.org/suppdata/dt/b4/b402602k/ (pp. 1563-1566) Galindo, Miguel A.; Navarro, Jorge A. R.; Romero, M. Angustias; Quirós, Miguel
• Synthetic and structural experiments on yttrium, cerium and magnesium trimethylsilylmethyls and their reaction products with nitriles; with a note on two cerium β-diketiminates (pp. 1567-1577) Avent, Anthony G.; Caro, Catherine. F.; Hitchcock, Peter B.; Lappert, Michael F.; Li, Zhengning; Wei, Xue-Hong
• Synthesis, structure, and ethene polymerisation catalysis of 1- or 2-silyl substituted bis[indenyl]zirconium(iv) dichlorides (pp. 1578-1589) Möller, Andreas C.; Heyn, Richard H.; Blom, Richard; Swang, Ole; Görbitz, Carl Henrik; Kopf, Jürgen
• A novel dicationic phenoxaphosphino-modified Xantphos-type ligand: a ligand for highly active and selective, biphasic, rhodium catalysed hydroformylation in ionic liquids (pp. 1590-1596) Bronger, Raymond P. J.; Silva, Silvana M.; Kamer, Paul C. J.; van Leeuwen, Piet W. N. M.
• Cyclam-based dendrimers as ligands for lanthanide ionsElectronic supplementary information (ESI) available: Luminescence spectra of 1–3, before and after addition of a stoichiometric amount of Nd(CF3SO3)3 in CH3CN–CH2Cl2 (1 ∶ 1 v/v) at 298 K with λexc = 275 nm. See http://www.rsc.org/suppdata/dt/b4/b403664f/ (pp. 1597-1600) Saudan, Christophe; Ceroni, Paola; Vicinelli, Veronica; Maestri, Mauro; Balzani, Vincenzo; Gorka, Marius; Lee, Sang-Kyu; Heyst, Jeroen van; Vögtle, Fritz
• Preparation, structures and some reactions of novel diynyl complexes of iron and ruthenium (pp. 1601-1609) Bruce, Michael I.; Ellis, Benjamin G.; Gaudio, Maryka; Lapinte, Claude; Melino, Giovanni; Paul, Frédéric; Skelton, Brian W.; Smith, Mark E.; Toupet, Loic; White, Allan H.
• Unsuccessful/successful attempts to produce penta(heteroaryl)-phosphoranes/-arsoranes R5E (E = P, As; R = 2-furyl, 2-thienyl) (pp. 1610-1617) Monkowius, Uwe V.; Nogai, Stefan; Schmidbaur, Hubert
• Synthesis and structural characterization of silanethiolato complexes having tert-butyldimethylsilyl and trimethylsilyl groups (pp. 1618-1625) Komuro, Takashi; Matsuo, Tsukasa; Kawaguchi, Hiroyuki; Tatsumi, Kazuyuki
• Cobalt tris(mercaptoimidazolyl)borate complexes: synthetic studies and the structure of the first cobaltaboratrane (pp. 1626-1634) Mihalcik, David J.; White, Jennifer L.; TanskiCurrent address: Department of Chemistry, Vassar College, 124 Raymond Avenue, Box 601, Poughkeepsie, New York, 12604, USA., Joseph M.; ZakharovCurrent address: Department of Chemistry and Biochemistry, University of California – San Diego, 9500 Gilman Drive, La Jolla, California 92093, USA., Lev N.; Yap, Glenn P. A.; IncarvitoCurrent address: Department of Chemistry, Yale University, New Haven, Connecticut 06520, USA., Christopher D.; Rheingold, Arnold L.; Rabinovich, Daniel
• Synthesis and crystal structure of uranium(iv) complexes with compartmental Schiff bases: from mononuclear species to tri- and tetranuclear clusters (pp. 1635-1643) Salmon, Lionel; Thuéry, Pierre; Ephritikhine, Michel
• Perfluoroalkylphosphine coordination chemistry of platinum: synthesis of (C2F5)2PPh and (C2F5)PPh2 complexes of platinum(ii) (pp. 1644-1647) Palcic, Jason D.; Kapoor, P. N.; Roddick, Dean M.; Gregory Peters, R.
• Quantifying the relative contribution of hydrogen bonding and hydrophobic environments, and coordinating groups, in the zinc(ii)–water acidity by synthetic modelling chemistryElectronic supplementary information (ESI) available: Speciation diagrams for a mixture of 1 mM L′1/L′3 + 1 mM Zn2+ and as a function of pH at 25 ºC with I = 0.1 (NaNO3). See http://www.rsc.org/suppdata/dt/b4/b402084g/ (pp. 1648-1655) Mareque-Rivas, Juan C.; Prabaharan, Ravi; Parsons, Simon
• Various forms of linear dipyridyls in discrete rectangles, dinuclear rods, and one-dimensional networks containing (η5-pentamethylcyclopentadienyl)rhodium(iii) (pp. 1656-1663) Seok Han, Won; Lee, Soon W.

Issue: 11

• New class of potent catalysts of O2˙− dismutation. Mn(iii) ortho-methoxyethylpyridyl- and di-ortho-methoxyethylimidazolylporphyrinsElectronic supplementary information (ESI) available: ESMS spectra along with corresponding tables. See http://www.rsc.org/suppdata/dt/b4/b400818a/ (pp. 1696-1702) Batinić-Haberle, Ines; Spasojević, Ivan; Stevens, Robert D.; Hambright, Peter; Neta, Pedatsur; Okado-Matsumoto, Ayako; Fridovich, Irwin
• Electron transfer reactions between copper(ii) porphyrin complexes and various oxidizing reagents in acetonitrileElectronic supplementary information (ESI) available: Figures reporting the UV-visible absorption spectra of [Cu(OEP)] and the product of the reaction of [Cu(OEP)] with Cu(ii) triflate in acetonitrile, the dependence of the absorbance on the ratio of the total concentrations of Cu(ii) ion and [Cu(OEP)] for the reaction of [Cu(OEP)] and Cu(ii) triflate, and the dependence of the pseudo-first-order rate constant of the reaction of [Fe(phen)3]3+ with [Ni(tacn)2]2+ on the concentration of the Ni(ii) complex. Tables of the second-order rate constant of the reaction of [Fe(phen)3]3+ with [Ni(tacn)2]2+ and the electron transfer properties of the complexes used in the present study. See http://www.rsc.org/suppdata/dt/b4/b403760j/ (pp. 1703-1707) Inamo, Masahiko; Kumagai, Hideto; Harada, Ushio; Itoh, Sumitaka; Iwatsuki, Satoshi; Ishihara, Koji; Takagi, Hideo D.
• Molecular structure of tris(dipivaloylmethanato)lutetium(iii) studied by gas electron diffraction and ab initio and DFT calculations (pp. 1715-1718) Belova, Natalya V.; Girichev, Georgiy V.; Hinchley, Sarah L.; Kuzmina, Natalya P.; Rankin, David W. H.; Zaitzeva, Irina G.
• Synthesis, structure and electrochemistry of ferrocene–peptide macrocyclesElectronic supplementary information (ESI) available: Figures and tables of spectroscopic results for compounds 5–9. See http://www.rsc.org/suppdata/dt/b4/b401039f/ (pp. 1726-1730) Chowdhury, Somenath; Schatte, Gabriele; Kraatz, Heinz-Bernhard
• Synthesis of photo-luminescent Zn(ii) Schiff base complexes and its derivative containing Pd(ii) moiety (pp. 1731-1738) Chang, Ku-Hsien; Huang, Chiung-Cheng; Liu, Yi-Hung; Hu, Ya-Hui; Chou, Pi-Tai; Lin, Ying-Chih
• Bis-dinuclear (Cu–Gd)2 complexes with a probable helicate structure (pp. 1739-1742) Novitchi, Ghenadie; Costes, Jean-Pierre; Tuchagues, Jean-Pierre
• Reactions of 2,4-hexadiyne-1,6-diol with [H2Os3(CO)9(PR3)] clusters. Cyclization of the diyne and reversible exchange of the phosphine ligands between different positions of the “Os3C3” frameworkElectronic supplementary information (ESI) available: Tables S1–S36: Crystallographic data, atomic coordinates, bond lengths, bond angles, anisotropic displacement parameters, hydrogen coordinates and isotropic displacement parameters, and torsion angles for clusters IV, V, Va, VI, VIIa and VIII. See http://www.rsc.org/suppdata/dt/b4/b403861b/ (pp. 1775-1782) Tunik, Sergey P.; Khripun, Vassily D.; Haukka, Matti; Pakkanen, Tapani A.

Issue: 12

• Recycling asymmetric hydrogenation catalysts by their immobilisation onto ion-exchange resinsElectronic supplementary information (ESI) available: Experimental section, 31P{1H} HP NMR spectra, typical EDS surface area spectrum and ESEM images. See http://www.rsc.org/suppdata/dt/b4/b406179a/ (pp. 1783-1784) Barbaro, Pierluigi; Bianchini, Claudio; Giambastiani, Giuliano; Oberhauser, Werner; Bonzi, Laura Morassi; Rossi, Filippo; Dal Santo, Vladimiro
• A novel self-assembling synthesis and crystal structure of 40-membered macrocyclic complex containing eight-tin (pp. 1785-1786) Ma, Chunlin; Sun, Jiafeng
• A nanoscale slipped sandwich of Tb10-stabilization of a benzaldehyde methyl hemiacetyl (pp. 1787-1788) Yang, Xiaoping; Jones, Richard A.; Wiester, Michael J.
• Computer simulation of nickel in blood-plasma following the in vitro investigations of complex formation chemistry with polyamine(amide) ligands (pp. 1789-1796) Nomkoko, Edmund T.; Jackson, Graham E.; Nakani, Bandile S.; Bourne, Susan A.
• Establishing the NO oxidation state in complexes [Cl5(NO)M]n−, M = Ru or Ir, through experiments and DFT calculations (pp. 1797-1800) Sieger, Monika; Sarkar, Biprajit; Záliš, Stanislav; Fiedler, Jan; Escola, Natalia; Doctorovich, Fabio; Olabe, José A.; Kaim, Wolfgang
• Gold–thallium supramolecular arrays with 4,4′-bipyridine. Solvent induction of luminescent networks (pp. 1801-1806) Fernández, Eduardo J.; Laguna, Antonio; López-de-Luzuriaga, José María; Olmos, M. Elena; Pérez, Javier
• Guest sorption and desorption in the metal–organic framework [Co(INA)2] (INA = isonicotinate) – evidence of intermediate phases during desorptionElectronic supplementary information (ESI) available: TGA for compounds 1 and 3. See http://www.rsc.org/suppdata/dt/b4/b404485a/ (pp. 1807-1811) Wei, Qiang; Nieuwenhuyzen, Mark; Meunier, Frederick; Hardacre, Chris; James, Stuart L.
• Bis- and tris-(methylphosphonic) acid derivatives of a 14-membered tetraazamacrocycle containing pyridine: synthesis, protonation and complexation studiesElectronic supplementary information (ESI) available: Molecular dynamics. See http://www.rsc.org/suppdata/dt/b4/b403977g/ (pp. 1812-1822) Guerra, Krassimira P.; Delgado, Rita; Lima, Luís M. P.; Drew, Michael G. B.; Félix, Vítor
• Novel unsymmetrical P/O substituted ferrocene ligands and the first structurally characterised hydroxyferrocene derivativeElectronic supplementary information (ESI) available: Fig. S1: Molecular structure of 3; Fig. S2: Molecular structure of 4 (50% probability ellipsoids). See http://www.rsc.org/suppdata/dt/b4/b403862b/ (pp. 1823-1826) Atkinson, Robert C. J.; Gibson, Vernon C.; Long, Nicholas J.; White, Andrew J. P.; Williams, David J.
• Designed synthesis of a multimetallic system having Ru4Cu2 core using trimetallic coordination of 2,2′-biimidazolate ionElectronic supplementary information (ESI) available: Fig. S1: EPR spectrum of 3 in 1 : 1 dichloromethane–toluene solution at 77 K (DPPH = diphenylpicrylhydrazyl). Fig. S2: Segmented cyclic and differential pulse voltammogram of 3. See http://www.rsc.org/suppdata/dt/b4/b404222k/ (pp. 1827-1831) Kamar, Kunal K.; Falvello, Larry R.; Fanwick, Philip E.; Kim, Jinkwon; Goswami, Sreebrata
• Self-assembly of diorganotin(iv) moieties and 2-pyrazinecarboxylic acid: syntheses, characterizations and crystal structures of monomeric, polymeric or trinuclear macrocyclic compounds (pp. 1832-1840) Ma, Chunlin; Han, Yinfeng; Zhang, Rufen; Wang, Daqi
• The formation, reactivity and interconversion of novel η1- and η3-triazacyclononane complexes of rhodium(i) and rhodium(iii) (pp. 1841-1845) Gott, Andrew L.; McGowan, Patrick C.; Temple, Claire N.
• Synthesis of di-, tri- and penta-nuclear titanium(iv) species from reactions of titanium(iv) alkoxides with 2,2′-biphenol (H2L1) and 1,1′-binaphthol (H2L2); crystal structures of [Ti3(μ2-OPri)2(OPri)8L1], [Ti3(OPri)6L13], [Ti5(μ3-O)2(μ2-OR)2(OR)6L14] (R = OPri, OBun) and [Ti2(OPri)4L22] (pp. 1846-1851) Corden, Jonathan P.; Errington, William; Moore, Peter; Partridge, Martin G.; Wallbridge, Malcolm G. H.
• Ordered binary crystals via cocrystallisation of quasiracemic Pd(ii) complexes in a borderline regime between inertness and lability (pp. 1852-1857) Calmuschi, Beatrice; Alesi, Maria; Englert, Ulli
• Reactions of octacyanomolybdate(v) and octacyanotungstate(v) with s2 metal-ion reducing centersElectron Transfer. Part 158.1Electronic supplementary information (ESI) available: Tables S1–S4; detailed kinetic data for redox reactions. See http://www.rsc.org/suppdata/dt/b4/b402460p/ (pp. 1858-1861) Yang, Zhiyong; Gould, Edwin S.
• Oxidation reaction of [Ni(1,4,7-triazacyclononane)2]2+ by [Fe(o-phenanthroline)3]3+ in aqueous acidic solution at elevated pressures: determination of the activation and reaction volumes for the Ni(iii)/(ii) coupleElectronic supplementary information (ESI) available: Tables S1–S3. See http://www.rsc.org/suppdata/dt/b4/b401969e/ (pp. 1862-1866) Itoh, Sumitaka; Koshino, Nobuyoshi; Katsuki, Masumi; Noda, Toshiaki; Ishihara, Koji; Inamo, Masahiko; Takagi, Hideo D.
• Polynuclear and 1-D derivatives of 1,3-bis(dimethylamino)-2-propanolato ligand. Structure and magnetic characterization (pp. 1867-1872) Escuer, Albert; El Fallah, M. Salah; Vicente, Ramon; Sanz, Núria; Font-Bardia, Mercé; Solans, Xavier; Mautner, Franz A.
• A new route to achiral and chiral 1,2-bis(phosphino)ethanes, 1-arsino-2-phosphinoethanes, and 1,3-bis(phosphino)propanes and the molecular structure and catalytic activity of some rhodium(i) complexes derived thereof Dedicated to Professor Wolfdieter A. Schenk, a respected colleague and creative scientist, on the occasion of his 60th birthday. (pp. 1873-1881) Fries, Guido; Wolf, Justin; Ilg, Kerstin; Walfort, Bernhard; Stalke, Dietmar; Werner, Helmut
• Vanadium(iv,v) complexes of d-saccharic and mucic acids in aqueous solutionElectronic supplementary information (ESI) available: Figs. S1–8: EPR spectra, calculated HyperChem structures, 51V and 1H NMR spectra. See http://www.rsc.org/suppdata/dt/b4/b401443j/ (pp. 1882-1891) Dörnyei, Ágnes; Garribba, Eugenio; Jakusch, Tamás; Forgó, Péter; Micera, Giovanni; Kiss, Tamás
• NMR and chiroptical examination of the diastereoisomers of (S)-Eu–EOB–DTPAElectronic supplementary information (ESI) available: Variable temperature proton NMR spectra (300 MHz, D2O) of the stereoisomeric mixture of (S)-Eu–EOB–DTPA. See http://www.rsc.org/suppdata/dt/b4/b403863k/ (pp. 1892-1895) Thompson, Nicola C.; Parker, David; Schmitt-Willich, Heribert; Sülzle, Detlev; Muller, Gilles; Riehl, James P.
• Bis(dipyridophenazine)copper(ii) complex as major groove directing synthetic hydrolase (pp. 1896-1900) Gupta, Tarkeshwar; Dhar, Shanta; Nethaji, Munirathinam; Chakravarty, Akhil R.
• Efficient asymmetric hydrogenation with rhodium complexes of C1-symmetric 2,5-dimethylphospholane-diphenylphosphines (pp. 1901-1905) Basra, Sandeep; de Vries, Johannes G.; Hyett, David J.; Harrison, Gayle; Heslop, Katie M.; Orpen, A. Guy; Pringle, Paul G.; von der Luehe, Karl

Issue: 13

• Biological inorganic and bioinorganic chemistry of neurodegeneration based on prion and Alzheimer diseases (pp. 1907-1917) Brown, David R.; Kozlowski, Henryk
• Electrochemical probing of ground state electronic interactions in polynuclear complexes of a new heteroditopic ligand (pp. 1918-1927) Constable, Edwin C.; Figgemeier, Egbert; Housecroft, Catherine E.; Olsson, Jerry; Zimmermann, Yves C.
• A bifurcated pathway of oxygen atom transfer reactions from a monooxo molybdenum(vi) complex under electrospray ionisation mass spectrometric conditions (pp. 1928-1933) Nemykin, Victor N.; Basu, Partha
• Co-ordination chemistry of amino pendant arm derivatives of 1,4,7-triazacyclononane (pp. 1934-1944) Tei, Lorenzo; Bencini, Andrea; Blake, Alexander J.; Lippolis, Vito; Perra, Alessandro; Valtancoli, Barbara; Wilson, Claire; Schröder, Martin
• Lanthanide complexes of new nonadentate imino-phosphonate ligands derived from 1,4,7-triazacyclononane: synthesis, structural characterisation and NMR studies (pp. 1945-1952) Tei, Lorenzo; Blake, Alexander J.; Wilson, Claire; Schröder, Martin
• Conformational and stereochemical flexibility in cadmium(ii) complexes of aza-thioether macrocycles (pp. 1953-1959) Glenny, Mark W.; van de Water, Leon G. A.; Driessen, Willem L.; Reedijk, Jan; Blake, Alexander J.; Wilson, Claire; Schröder, Martin
• Early–late, mixed-metal compounds supported by amidophosphine ligandsElectronic supplementary information (ESI) available: Tables of crystal data and selected bond lengths and angles, plus Ortep diagrams of complexes 9 and 10. See http://www.rsc.org/suppdata/dt/b4/b402409e/ (pp. 1960-1970) Mokuolu, Q. Folashade; Duckmanton, Paul A.; Hitchcock, Peter B.; Wilson, Claire; Blake, Alexander J.; Shukla, Lena; Love, Jason B.
• Reduction reactions of a 1,3,5-triphosphabenzene (pp. 1971-1979) Jones, Cameron; Waugh, Mark
• Structures of the radical P[N(SiMe3)2](NPri2), its dimer, cation and chloro derivativeElectronic supplementary information (ESI) available: The final Cartesian coordinates of the computed structures of the diphosphine 2 and the corresponding radical 3, a selected list of distances and associated amplitudes of vibrations and the correlation matrix from the electron diffraction least-squares refinements. See http://www.rsc.org/suppdata/dt/b4/b402926g/ (pp. 1980-1988) Bezombes, Jean-Philippe; Borisenko, Konstantin B.; Hitchcock, Peter B.; Lappert, Michael F.; Nycz, Jacek E.; Rankin, David W. H.; Robertson, Heather E.
• Organotin and organogermanium linkers for simple, direct functionalization of polyoxotungstatesElectronic supplementary information (ESI) available: syntheses. See http://www.rsc.org/suppdata/dt/b4/b402421d/ (pp. 1989-1994) Sazani, Gerta; Pope, Michael T.
• Governing the oxidative addition of iodine to gold(i) complexes by ligand tuning (pp. 1995-2005) Schneider, Daniel; Schier, Annette; Schmidbaur, Hubert
• Carboxylic acid functionalized cobalt(iii) cyclen complexes for catalytic hydrolysis of phosphodiester bonds (pp. 2006-2011) Andrew Knight, D.; Delehanty, James B.; Goldman, Ellen R.; Bongard, Jason; Streich, Frederick; Edwards, Laura W.; Chang, Eddie L.
• Cationic lanthanide complexes of neutral tripodal N,O ligands: enthalpy versus entropy-driven podate formation in waterElectronic supplementary information (ESI) available: Plots of δparai,Ln/〈SZ〉Ln vs. DLn/〈SZ〉Ln for proton H3 in [Ln(tpaam)]3+ podates in D2O at 298 K (Fig. S1). Plots of δparai,Ln/〈SZ〉Ln vs. δparak,Ln/〈SZ〉Ln for the H3–H5 and H7–H5 pairs in [Ln(tpaam)]3+ podates in D2O at 298 K (Fig. S2).Van't Hoff plots for europium complexation by tpa and tpaam in water (ionic strength 1 mol L−1 KCl) (Fig. S3). See http://www.rsc.org/suppdata/dt/b4/b403647f/ (pp. 2012-2018) Bravard, Florence; Rosset, Caroline; Delangle, Pascale
• Reactions of thiosemicarbazones derived from β-keto amides and β-keto esters with Zn(ii) and Cd(ii) acetates: influence of metal, substitution, reagent ratio and temperature on metal-induced cyclizationElectronic supplementary information (ESI) available: SM1: Analytical and spectroscopic data for the ligands. ST1: Complexes obtained in the assayed experimental conditions. ST2: IR spectra of the new complexes. ST3: 1H NMR spectra of the new HTSCn and HLn complexes. ST4: 13C and 113Cd NMR spectra of some new complexes. ST5: Hydrogen bond lengths (Å) and angles (°) in ligands and complexes. SF1: Intermolecular interactions in [CdL52(DMSO)]·DMSO. SF2: (a) 1H NMR spectrum of [Cd(TSC4)2] at room temperature; (b) 1H NMR spectrum of the same sample after 1 h heating at 90 °C. SF3: O 1s core level spectra for [ZnL42]·H2O and [Zn(L4 − H)]. See http://www.rsc.org/suppdata/dt/b4/b401674b/ (pp. 2019-2026) Casas, José S.; Castaño, María V.; García-Tasende, María S.; Rodríguez-Castellón, Enrique; Sánchez, Agustín; Sanjuán, Luisa M.; Sordo, José
• Multinuclear (1H, 31P and 195Pt) NMR study and dynamical analysis of binuclear µ-hydrido µ-carbonyl Pt(i) cations with chelating diphosphinesElectronic supplementary information (ESI) available: Fig. S1: Effect of kII and kIII on the dynamical NMR lineshape computed for the four-site exchange model. Fig. S2: Linewidth contributions to hydride NMR spectra of complex 3 as a function of temperature. Fig. S3: Selected 31P VT-NMR spectra for complex 3. Fig. S4: 195Pt spectrum of 1. See http://www.rsc.org/suppdata/dt/b3/b316868a/ (pp. 2027-2035) Bandini, Anna L.; Banditelli, Guido; Grassi, Maria; Ponti, Alessandro
• Synergistic effect of Ni(ii) and Co(ii) ions on the sulfite induced autoxidation of Cu(ii)/tetraglycine complex (pp. 2036-2040) Alipázaga, María V.; Moreno, Rubén G. M.; Coichev, Nina
• N-benzoylimido complexes of palladium. Synthesis, structural characterisation and structure–reactivity relationship (pp. 2041-2050) Besenyei, Gábor; Párkányi, László; Szalontai, Gábor; Holly, Sándor; Pápai, Imre; Keresztury, Gábor; Nagy, Andrea

Issue: 14

• Vitamin B12 as an allosteric cofactor; dual fluorescence, hysteresis, oscillations and the selection of corrin over porphyrinThe chemistry of vitamin B12. Part 32. For part 31, see ref. 1. (pp. 2125-2134) Chemaly, Susan M.; Jack, Lorna A.; Yellowlees, Lesley J.; Harper, Pascal L. S.; Heeg, Bauke; Pratt, John M.
• Dynamic NMR properties of DOTA ligand: variable pH and temperature 1H NMR study on [K(HxDOTA)](3−x)− speciesElectronic supplementary information (ESI) available: Figs. S1–3: 2D COSY spectrum of [K(DOTA)]3− at pH 13 and 260 K, experimental 1H-spectra and results of the model-calculations for some temperatures at pH 13, Eyring plot for determining the activation parameters of water–[K(HxDOTA)](3−x)− proton exchange at pH 3.87 and 4.31. See http://www.rsc.org/suppdata/dt/b4/b405116e/ (pp. 2152-2156) Csajbók, Éva; Bányai, István; Brücher, Ernő

Issue: 16

• Investigations on the electronic effects of the peripheral 4′-group on 5-(4′-substituted)phenylazo-8-hydroxyquinoline ligands: zinc and aluminium complexesElectronic supplementary information (ESI) available: synthesis details of ligands I–VI, complexes 1a–6a and 2b–6b, absorption maxima from electronic spectra of compounds I–VI, 1a–6a and 1b–6b, emission spectra of complexes 1a and 1b, Cartesian coordinates of neutral and charged ligands I, A, V and VI, the Kohn–Sham orbital energies and the HOMO–LUMO gaps for compounds I, A, V and VI, and atomic spin density for two nitrogen atoms of the diazo group and the computed geometries of the neutral and charged compounds I, A, V and VI. See http://www.rsc.org/suppdata/dt/b4/b404814h/ (pp. 2424-2431) La Deda, Massimo; Grisolia, Annarita; Aiello, Iolinda; Crispini, Alessandra; Ghedini, Mauro; Belviso, Sandra; Amati, Mario; Lelj, Francesco
• Synthesis, spectroscopic and structural properties of hexavalent molybdenum complexes with thio- and seleno-ether ligands (pp. 2487-2491) Brown, Michael D.; Hursthouse, Michael B.; Levason, William; Ratnani, Raju; Reid, Gillian
• Synthesis and studies of a trinuclear Mn(ii) carboxylate complex (pp. 2550-2555) Christian, Paul; Rajaraman, Gopalan; Harrison, Andrew; Helliwell, Madeleine; McDouall, Joseph J. W.; Raftery, James; Winpenny, Richard E. P.

Issue: 17

• Intramolecularly hydrogen-bonded versus copper(ii) coordinated mono- and bis-phenoxyl radicalsElectronic supplementary information (ESI) available: Structural characterisation of a related ligand (H2L5), catalytic activity of [CuII(L1–4)]˙+, Figs. S1–S9. See http://www.rsc.org/suppdata/dt/b4/b406009a/ (pp. 2662-2669) Thomas, Fabrice; Jarjayes, Olivier; Duboc, Carole; Philouze, Christian; Saint-Aman, Eric; Pierre, Jean-Louis
• Nickel pivalate complexes: structural variations and magnetic susceptibility and inelastic neutron scattering studies (pp. 2758-2766) Chaboussant, Grégory; Basler, Reto; Güdel, Hans-Ulrich; Ochsenbein, Stefan; Parkin, Andrew; Parsons, Simon; Rajaraman, Gopalan; Sieber, Andreas; Smith, Andrew A.; Timco, Grigore A.; Winpenny, Richard E. P.
• Exo-π-bonding to an ortho-carborane hypercarbon atom: systematic icosahedral cage distortions reflected in the structures of the fluoro-, hydroxy- and amino-carboranes, 1-X-2-Ph-1,2-C2B10H10 (X = F, OH or NH2) and related anionsElectronic supplementary information (ESI) available: CIF file for five ortho-carborane derivatives. Tables of energies for MP2/6–31G* optimised geometries, selected structural data for the aminocarborane PhCb°NH2 and for biscarborane derivatives. See http://www.rsc.org/suppdata/dt/b4/b406422d/ (pp. 2786-2799) Boyd, Lynn A.; Clegg, William; Copley, Royston C. B.; Davidson, Matthew G.; Fox, Mark A.; Hibbert, Thomas G.; Howard, Judith A. K.; Mackinnon, Angus; Peace, Richard J.; Wade, Kenneth

Issue: 19

• Dalton Discussion No. 7: Ionic and electronic properties of solids (p. E4)
• Schizophrenic electrons in ruthenium-based oxidesBased on the presentation given at Dalton Discussion No. 7, 5–7th July 2004, University of St Andrews, UK. (pp. 2979-2987) Cava, R. J.
• Various strategies to tune the ionic/electronic properties of electrode materialsBased on the presentation given at Dalton Discussion No. 7, 5–7th July 2004, University of St Andrews, UK. (pp. 2988-2994) Tarascon, J. M.; Delacourt, C.; Prakash, A. S.; Morcrette, M.; Hegde, M. S.; Wurm, C.; Masquelier, C.
• Electronic phase separation in transition metal oxide systemsBased on the presentation given at Dalton Discussion No. 7, 5–7th July 2004, University of St Andrews, UK. (pp. 3003-3011) Rao, C. N. R.; Kundu, Asish K.; Seikh, Md. Motin; Sudheendra, L.
• Hydrogen in oxidesBased on the presentation given at Dalton Discussion No. 7, 5–7th July 2004, University of St Andrews, UK. (pp. 3012-3018) Norby, Truls; Widerøe, Marius; GlöcknerPresent address: Institute for Energy Technology, POB 40, NO-2007 Kjeller, Norway., Ronny; LarringPresent address: SINTEF Materials Technology, POB 124, NO-0314 Oslo, Norway., Yngve
• Spin dimer and classical spin analyses of the ordered magnetic structures of alkali iron pyrophosphates NaFeP2O7 and LiFeP2O7Based on the presentation given at Dalton Discussion No. 7, 5–7th July 2004, University of St Andrews, UK. (pp. 3019-3025) Whangbo, Myung-Hwan; Dai, Dadi; KooPresent address: Department of Chemistry, KyungHee University, Seoul 130-701, South Korea., Hyun-Joo
• Phase separation in manganites induced by orbital–ordering strainsBased on the presentation given at Dalton Discussion No. 7, 5–7th July 2004, University of St Andrews, UK. (pp. 3026-3031) Chapman, Jon P.; Attfield, J. Paul; Rodriguez-Martinez, Lide M.; Lezama, Luis; Rojo, Teófilo
• The pyrochlore family – a potential panacea for the frustrated perovskite chemistBased on the presentation given at Dalton Discussion No. 7, 5–7th July 2004, University of St Andrews, UK. (pp. 3032-3041) Weller, Mark T.; Hughes, Robert W.; Rooke, Joanna; Knee, Christopher S.; Reading, Jon
• Li+ ion conductivity in rock salt-structured nickel-doped Li3NbO4Based on the presentation given at Dalton Discussion No. 7, 5–7th July 2004, University of St Andrews, UK. (pp. 3042-3047) McLaren, Victoria L.; Kirk, Caroline A.; Poisot, Martha; Castellanos, Maria; West, Anthony R.
• Solid-state NMR study of the anionic conductor Ca-doped Y2Ti2O7Based on the presentation given at Dalton Discussion No. 7, 5–7th July 2004, University of St Andrews, UK. (pp. 3048-3052) Kim, Namjun; Grey, Clare P.
• Structure and inter-phase stability in solvent-free low-dimensional polymer electrolytes with high lithium conductivityBased on the presentation given at Dalton Discussion No. 7, 5–7th July 2004, University of St Andrews, UK. (pp. 3053-3060) Zheng, Yungui; Liu, Jianguo; Liao, Yen-Po; Ungar, Goran; Wright, Peter V.
• Doping and defect association in AZrO3 (A = Ca, Ba) and LaMO3 (M = Sc, Ga) perovskite-type ionic conductorsBased on the presentation given at Dalton Discussion No. 7, 5–7th July 2004, University of St Andrews, UK. (pp. 3061-3066) Islam, M. Saiful; Slater, Peter R.; Tolchard, Julian R.; DingesPresent address: Fachhochschule Gelsenkirchen, D45665 Recklinghausen, Germany., Tim
• What variable-pressure variable-temperature measurements are telling us about ion transport in glass (pp. 3067-3070) Imrie, Based on the presentation given at Dalton Discussion No. 7, 5–7th July 2004, University of St Andrews, UK.Corrie T.; Konidakis, Ioannis; Ingram, Malcolm D.
• Simulating surface diffusion and surface growth in ceramicsBased on the presentation given at Dalton Discussion No. 7, 5–7th July 2004, University of St Andrews, UK. (pp. 3071-3075) Lavrentiev, Mikhail Yu.; Harris, Duncan J.; Harding, John H.; Allan, Neil L.; Purton, John A.
• The interdependence of defects, electronic structure and surface chemistryBased on the presentation given at Dalton Discussion No. 7, 5–7th July 2004, University of St Andrews, UK. (pp. 3076-3084) Lindan, Philip; Duplock, Elizabeth; Zhang, Changjun; Thomas, Michelle; Chatten, Ryan; Chadwick, Alan
• Phosphorus carbides: theory and experimentBased on the presentation given at Dalton Discussion No. 7, 5–7th July 2004, University of St Andrews, UK.Electronic supplementary information (ESI) available: Space group information and optimised basis atom positions for hypothetical structures (A)–(H) for PC3. See http://www.rsc.org/suppdata/dt/b4/b402740j/ (pp. 3085-3092) Claeyssens, F.; Fuge, G. M.; Allan, N. L.; May, P. W.; Ashfold, M. N. R.
• Evolution of structure, transport properties and magnetism in ternary lithium nitridometalates Li3−x−yMxN, M = Co, Ni, CuBased on the presentation given at Dalton Discussion No. 7, 5–7th July 2004, University of St Andrews, UK.Electronic supplementary information (ESI) available: Powder X-ray diffraction pattern for LiNiN. Molar susceptibility as a function of temperature for Li2.6−yCo0.4N. See http://www.rsc.org/suppdata/dt/b4/b401272k/ (pp. 3093-3097) Stoeva, Zlatka; Gomez, Ruben; Gregory, Duncan H.; Hix, Gary B.; Titman, Jeremy J.
• Computer modelling of mixed metal fluorides for optical applicationsBased on the presentation given at Dalton Discussion No. 7, 5–7th July 2004, University of St Andrews, UK. (pp. 3098-3100) Jackson, Robert A.; Valerio, Mario E. G.; Couto dos Santos, Marcos A.; Amaral, Jomar B.
• Oxide ion diffusion in optimised LAMOX materialsBased on the presentation given at Dalton Discussion No. 7, 5–7th July 2004, University of St Andrews, UK. (pp. 3101-3105) Georges, Samuel; Skinner, Stephen J.; Lacorre, Phillippe; Steil, M Cesar
• Doping strategies to optimise the oxide ion conductivity in apatite-type ionic conductorsBased on the presentation given at Dalton Discussion No. 7, 5–7th July 2004, University of St Andrews, UK. (pp. 3106-3109) Najib, A.; Sansom, J. E. H.; Tolchard, J. R.; Slater, P. R.; Islam, M. S.
• Influence of synthesis route on the properties of doped lanthanum cobaltite and its performance as an electrochemical reactor for the partial oxidation of natural gasBased on the presentation given at Dalton Discussion No. 7, 5–7th July 2004, University of St Andrews, UK. (pp. 3110-3115) Richardson, Rebecca A.; Cotton, John W.; Mark Ormerod, R.
• Structure and reactivity of V2O5: bulk solid, nanosized clusters, species supported on silica and alumina, cluster cations and anionsBased on the presentation given at Dalton Discussion No. 7, 5–7th July 2004, University of St Andrews, UK. (pp. 3116-3121) Sauer, Joachim; Döbler, Jens
• Rubidium doped zeolite rho: structure and microwave conductivity of a metallic zeoliteBased on the presentation given at Dalton Discussion No. 7, 5–7th July 2004, University of St Andrews, UK. (pp. 3122-3128) Anderson, Paul A.; Armstrong, A. Robert; Barker, Peter D.; Edmondson, Michael J.; Edwards, Peter P.; Porch, Adrian
• Structural and electrical characterisation of Li2O ∶ TiO2 ∶ SnO2 ∶ P2O5 electrolyte glassBased on the presentation given at Dalton Discussion No. 7, 5–7th July 2004, University of St Andrews, UK. (pp. 3129-3136) Abrahams, Isaac; HadzifejzovicPresent address, Department of Chemistry, University College London, Christopher Ingold Laboratories, 20 Gordon Street, London, UK WC1H 0AJ., Emina; Dygas, Józef. R.
• Expanded fullerides and electron localisation – lithium-rich ammoniated C60 phasesElectronic supplementary information (ESI) available: Figs. S1–S12: Additional characterising data. Table S1: Structural parameters obtained from Rietveld refinement of the 350 °C data for Li3(NH3)6C60. See http://www.rsc.org/suppdata/dt/b4/b402817a/ (pp. 3137-3143) Durand, P.; Dubitsky, Y.; Rosseinsky, M. J.; Zaopo, A.
• Lattice collapse in mixed-valence samarium fulleride Sm2.75C60 at high pressureBased on the presentation given at Dalton Discussion No. 7, 5–7th July 2004, University of St Andrews, UK. (pp. 3144-3146) Arvanitidis, J.; Papagelis, Konstantinos; Margadonna, Serena; Prassides, Kosmas
• Transport numbers from hydrogen concentration cells over different oxides under oxidising and reducing conditionsBased on the presentation given at Dalton Discussion No. 7, 5–7th July 2004, University of St Andrews, UK. (pp. 3147-3151) Widerøe, Marius; Kochetova, Nadezhda; Norby, Truls

Issue: 20

• ReSourCe—a new web service for authors and referees (pp. E11-E11)
• Rare and unexpected coordination to copper(ii) by a tertiary amide in a macrocyclic ligandElectronic supplementary information (ESI) available: Synthesis and spectral characterization of 4. See http://www.rsc.org/suppdata/dt/b4/b410525g/ (pp. 3163-3165) Sibbons, Kevin F.; Al-Hashimi, Mohammed; Motevalli, Majid; Wolowska, Joanna; Watkinson, Michael
• Solution- and solid-state characterisation of a configurationally-stable β-diketiminato-supported calcium primary amideElectronic supplementary information (ESI) available: NMR spectrum of reaction of 1 in C6D6 with one equivalent of methoxyethylamine. See http://www.rsc.org/suppdata/dt/b4/b412060d/ (pp. 3166-3168) Avent, Anthony G.; Crimmin, Mark R.; Hill, Michael S.; Hitchcock, Peter B.
• A new synthetic route to metal trithiophosphonates: Syntheses and structures of [(C6H11)PS3Li2·THF·TMEDA]2 and [(C6H11)PS3Mg·2THF]2Electronic supplementary information (ESI) available: Molecular structure of 4 and 5; in situ 31P{1H} NMR spectroscopic study of the formation of 4. See http://www.rsc.org/suppdata/dt/b4/b412488j/ (pp. 3169-3170) Bjernemose, Jens K.; Davies, Robert P.; Jurd, Andrew P. S.; Martinelli, M. Giovanna; Raithby, Paul R.; White, Andrew J. P.
• Anomalous structure–luminescence relationship in phosphorescent gold(i) isonitrile neutral complexes (pp. 3173-3175) Elbjeirami, Oussama; Omary, Mohammad A.; Stender, Matthias; Balch, Alan L.
• Metal-induced formation of a new chiral bidentate N,O ligand and the synthesis of novel monomeric germylenesElectronic supplementary information (ESI) available: synthesis and characterisation of 2, 3′, 4 and 5. See http://www.rsc.org/suppdata/dt/b4/b411889h/ (pp. 3176-3177) Driess, Matthias; Dona, Nicoleta; Merz, Klaus
• Intramolecular reduction of the nitro group into phosphoraneimine mediated by a rhenium(v) complex. Synthesis and structure of the novel phosphoraneimine oxorhenium(v) complex [ReOCl{o-(PPh3N)C6H4(NCH2CH2N(CH2CO2H)CH2CO2)}] (pp. 3178-3180) Allali, M.; Benoist, E.; Gressier, M.; Jaud, J.; Habbadi, N.; Souizi, A.; Dartiguenave, M.
• New route to a face-to-face biscorrole free-base and the corresponding heterobimetallic copper(iii)–silver(iii) complexElectronic supplementary information (ESI) available: Experimental data. Fig. S1: UV-Vis spectra of Cu2-1, Ag2-1 and AgCu-1. Table S1: Selected structural data for AgCu-1 and Cu2-1. See http://www.rsc.org/suppdata/dt/b4/b410249e/ (pp. 3181-3183) Pacholska, Ewa; Espinosa, Enrique; Guilard, Roger
• XAS characterization of end-on and side-on peroxoiron(iii) complexes of the neutral pentadentate N-donor ligand N-methyl-N,N′,N′-tris(2-pyridylmethyl)ethane-1,2-diamineElectronic supplementary information (ESI) available: Figs. S1 and S2 display additional isomers for 1 and 2, respectively. Fig. S3 displays the pre-edge regions of the Fe K-edge XAS data for 1A, 1B, [FeIII(N4Py)(η1-OOH)]2+, 2A, 2B, and [FeIII(N4Py)(η2-O2)]+, including the normalized data, the simulated absorption edge, and their difference. Fig. S4 displays the Fourier transforms and Fourier-filtered EXAFS spectra of the best fits to the EXAFS data for samples 1B and 2B (fit 7′, Table 2 and fit 7′, Table 3, respectively). See http://www.rsc.org/suppdata/dt/b4/b409727k/ (pp. 3191-3198) Koehntop, Kevin D.; Rohde, Jan-Uwe; Costas, Miquel; Que Jr., Lawrence
• Designing copper(ii) ternary complexes to generate radical cations of peptides in the gas phase: Role of the auxiliary ligandGas Phase Ion Chemistry of Biomolecules. Part 43. For part 42, see ref. 33. (pp. 3199-3204) Barlow, Christopher K.; Wee, Sheena; McFadyen, W. David; O'Hair, Richard A. J.
• Synthesis, properties and structures of eight-coordinate zirconium(iv) and hafnium(iv) halide complexes with phosphorus and arsenic ligands (pp. 3305-3312) Levason, William; Matthews, Melissa L.; Patel, Bhavesh; Reid, Gillian; Webster, Michael
• The preparation and characterisation of bimetallic iridium(ii) complexes containing derivatised bridging naphthalene-1,8-disulfur or 4,5-dithiolato acephenanthrylene ligands (pp. 3347-3352) Aucott, Stephen M.; Milton, Heather L.; Robertson, Stuart D.; Slawin, Alexandra M. Z.; Woollins, J. Derek
• Designing dinuclear iron(ii) spin crossover complexes. Structure and magnetism of dinitrile-, dicyanamido-, tricyanomethanide-, bipyrimidine- and tetrazine-bridged compounds (pp. 3370-3375) Batten, Stuart R.; Bjernemose, Jens; Jensen, Paul; Leita, Ben A.; Murray, Keith S.; Moubaraki, Boujemaa; Smith, Jonathan P.; Toftlund, Hans

Issue: 21

• The origin of chemoselectivity in the hydrocarbonylation of alkenes catalysed by trialkylphosphine complexes of rhodiumElectronic supplementary information (ESI) available: Experimetal section and selected NMR data for rhodium complexes. See http://www.rsc.org/suppdata/dt/b4/b412919a/ (pp. 3425-3427) Cheliatsidou, Paraskevi; White, Daniel F. S.; Cole-Hamilton, David J.
• Neutral and zwitterionic group 4 metal alkyls with ancillary boroxide ligands (pp. 3428-3430) Cole, Sarah C.; Coles, Martyn P.; Hitchcock, Peter B.
• Chromium(iii) and chromium(iv) bis(trimethylsilyl)amido complexes as ethylene polymerisation catalystsElectronic supplementary information (ESI) available: Experimental details. See http://www.rsc.org/suppdata/dt/b4/b412584c/ (pp. 3431-3433) Ballem, Katherine H. D.; Shetty, Vidhath; Etkin, Nola; Patrick, Brian O.; Smith, Kevin M.
• In situ formation of meso-2,2′-oxydisuccinate via intermolecular dehydration coupling of d,l-malic acid: first coordination polymer of 2,2′-oxydisuccinate involving ether oxygen coordination: [Cd2(meso-odsc)(H2O)]Electronic supplementary information (ESI) available: Fig. S1: simulated and measured XRPD patterns of 1. See http://www.rsc.org/suppdata/dt/b4/b410554k/ (pp. 3437-3439) Zhang, Xian-Ming; Hou, Juan-Juan; Wu, Hai-Shun
• The ligand, the metal and the ‘Holey’-host: Synthesis, structural and magnetic characterisation of Co(ii), Ni(ii) and Mn(ii) metal–organic frameworks incorporating 4,4′-dicarboxy-2,2′-bipyridine (pp. 3440-3447) Tynan, Eithne; Jensen, Paul; Kelly, Niamh R.; Kruger, Paul E.; Lees, Anthea C.; Moubaraki, Boujemaa; Murray, Keith S.
• Structures and anion-binding properties of M4L6 tetrahedral cage complexes with large central cavitiesElectronic supplementary information (ESI) available: Structure of part of the complex cation of [Co4(L3)6](BF4)8·6MeCN (S1) and [Co4(L3)6]I8·6MeCN·12.5H2O (S3); space-filling view of the complex cation of [Co4(L3)6](PF6)5.5F2.5·ca.5MeCN (S2); additional crystallographic details. See http://www.rsc.org/suppdata/dt/b4/b409809a/ (pp. 3453-3458) Paul, Rowena L.; Argent, Stephen P.; Jeffery, John C.; Harding, Lindsay P.; Lynam, Jason M.; Ward, Michael D.
• Effects of diphosphine structure on aurophilicity and luminescence in Au(i) complexesElectronic supplementary information (ESI) available: UV-Vis spectra of 1–6. See http://www.rsc.org/suppdata/dt/b4/b410619a/Dedicated to Prof. José Vicente on the occasion of his 60th birthday. (pp. 3459-3467) Pintado-Alba, Aranzazu; de la Riva, Héctor; Nieuwhuyzen, Mark; Bautista, Delia; Raithby, Paul R.; Sparkes, Hazel A.; Teat, Simon J.; López-de-Luzuriaga, José M.; Lagunas, M. Cristina
• Synthesis and coordination properties of new macrocyclic ligands: equilibrium studies and crystal structures (pp. 3468-3474) Ambrosi, Gianluca; Dapporto, Paolo; Formica, Mauro; Fusi, Vieri; Giorgi, Luca; Guerri, Annalisa; Micheloni, Mauro; Paoli, Paola; Pontellini, Roberto; Rossi, Patrizia
• Molecular precursors to gallium oxide thin films (pp. 3475-3480) Basharat, Siama; Carmalt, Claire J.; King, Simon J.; Peters, Emily S.; Tocher, Derek A.
• Syntheses, structures and magnetic properties of Mn(ii) dimers [CpMn(μ-X)]2 (Cp = C5H5; X = RNH, R1R2N, CCR)Electronic supplementary information (ESI) available: Derivation of magnetic susceptibility of MnII dimers including biquadratic exchange. See http://www.rsc.org/suppdata/dt/b4/b409135c/ (pp. 3481-3487) Alvarez, Carmen Soria; Boss, Sally R.; Burley, Jonathan C.; Humphry, Simon M.; Layfield, Richard A.; Kowenicki, Richard A.; McPartlin, Mary; Rawson, Jeremy M.; Wheatley, Andrew E. H.; Wood, Paul T.; Wright, Dominic S.
• Honeycombs, herringbones and brick-walls; three-fold guest-dependent variation in copper trimesate complexes bearing sulfimide ligands (pp. 3488-3494) Holmes, Kathryn E; Kelly, Paul F; Elsegood, Mark R J
• Stoichiometry, stability constants and coordination geometry of Eu(iii) 5-sulfosalicylate complex in aqueous system—A TRLIFS studyElectronic supplementary information (ESI) available: Fig. S1–S6. See http://www.rsc.org/suppdata/dt/b4/b407729f/ (pp. 3495-3502) Toraishi, Takashi; Aoyagi, Noboru; Nagasaki, Shinya; Tanaka, Satoru
• Ferromagnetic exchange in a dinuclear copper(ii) complex mediated by a methanolate bridging ligand (pp. 3503-3507) Fondo, Matilde; García-Deibe, Ana M.; Corbella, Montserrat; Ribas, Joan; Llamas-Saiz, Antonio; Bermejo, Manuel R.; Sanmartín, Jesús
• Monomeric, one- and two-dimensional networks incorporating (2,6-Me2C6H3S)2Pb building blocks (pp. 3515-3520) Appleton, Sarah E.; Briand, Glen G.; Decken, Andreas; Smith, Anita S.
• Condensation reactions of monomeric hydroxo palladium complexes with active methyl and methylene compoundsElectronic supplementary information (ESI) available: Table S1: 1H and 19F NMR data. See http://www.rsc.org/suppdata/dt/b4/b409942g/ (pp. 3521-3527) Ruiz, José; Martínez, M. Teresa; Rodríguez, Venancio; López, Gregorio; Pérez, José; Chaloner, Penny A.; Hitchcock, Peter B.
• Synthesis, structure and reactivity of palladium(ii) complexes of chiral N-heterocyclic carbene–imine and –amine hybrid ligands (pp. 3528-3535) Bonnet, Ludovic G.; Douthwaite, Richard E.; Hodgson, Richard; Houghton, Jennifer; Kariuki, Benson M.; Simonovic, Stevan
• Inside or outside a ligand cleft? Synthetic, structural, and kinetic inertness studies of zinc, cadmium, and mercury complexes of cross-bridged cyclam and cyclenDedicated to the memory of Professor Johan Springborg, a pioneer in polycyclic polyamine coordination chemistry. (pp. 3536-3547) Niu, Weijun; Wong, Edward H.; Weisman, Gary R.; Hill, Daniel C.; Tranchemontagne, David J.; Lam, Kim-Chung; Sommer, Roger D.; Zakharov, Lev N.; Rheingold, Arnold L.
• Synthesis and structures of aluminium monohydride and chalcogenides bearing a bidentate [N,O] ligand (pp. 3548-3551) Peng, Ying; Hao, Haijun; Jancik, Vojtech; Roesky, Herbert W.; Herbst-Irmer, Regine; Magull, Jörg
• Monocarbaborane anion chemistry. {COOH}, {CH2OH} and {CHO} units as functional groups on ten-vertex monocarbaborane anionic compounds (pp. 3552-3561) Franken, Andreas; Carr, Michael J.; Clegg, William; Kilner, Colin A.; Kennedy, John D.
• Energetics of the Preyssler anion's molecular orbitals: quantifying the effect of the encapsulated-cation's chargeElectronic supplementary information (ESI) available: Figs. S1 and S2. See http://www.rsc.org/suppdata/dt/b4/b412337a/ (pp. 3562-3567) Chiang, Ming-Hsi; Antonio, Mark R.; Soderholm, L.
• The structural characteristics of organozinc complexes incorporating N,N′-bidentate ligandsElectronic supplementary information (ESI) available: NMR spectroscopic data for 13 and selected crystallographic data for 8, 10, 12–14, and 16. See http://www.rsc.org/suppdata/dt/b4/b410945g/ (pp. 3568-3574) Birch, Samuel J.; Boss, Sally R.; Cole, Sarah C.; Coles, Martyn P.; Haigh, Robert; Hitchcock, Peter B.; Wheatley, Andrew E. H.
• Syntheses and chemistry of hypervalent cyclo-R4Sb4, cyclo-(RSbE)n [R = 2-(Me2NCH2)C6H4, E = O, S] and precursors (pp. 3575-3585) Opris, Laura M.; Silvestru, Anca; Silvestru, Cristian; Breunig, Hans J.; Lork, Enno
• Complexes of a novel multinucleating poly-β-diketonate ligandElectronic supplementary information (ESI) available: Figs. S1 and S2. See http://www.rsc.org/suppdata/dt/b4/b410481a/ (pp. 3586-3592) Aromí, Guillem; Boldron, Christophe; Gamez, Patrick; Roubeau, Olivier; Kooijman, Huub; Spek, Anthony L.; Stoeckli-Evans, Helen; Ribas, Joan; Reedijk, Jan
• Extraction and coordination studies of the unexplored bifunctional ligand carbamoyl methyl sulfoxide (CMSO) with uranium(vi) and cerium(iii) nitrates. Synthesis and structures of [UO2(NO3)2(PhSOCH2CONiBu2)] and [Ce(NO3)3(PhSOCH2CONBu2)2]Electronic supplementary information (ESI) available: TG/DTA for 8 and 10, ES-MS for 8 and 10 in acetone, 10 in CH2Cl2, log D vs. log [L6] plots for Pu(iv) and U(vi) and powder XRD patterns of the decomposed products of 8 and 10. See http://www.rsc.org/suppdata/dt/b4/b407824a/ (pp. 3604-3610) Kannan, Shanmugaperumal; Chetty, Kuna Venugopal; Venugopal, Venkatarama; Drew, Michael G. B.
• Synthesis and proposed crystal structure of a disordered cadmium arsenate apatite Cd5(AsO4)3Cl1−2x−yOx□xOHy (pp. 3611-3615) Johnson, Christopher D.; Feldmann, Jörg; Macphee, Donald E.; Worrall, Fred; Skakle, Janet M. S.
• A combined parahydrogen and theoretical study of H2 activation by 16-electron d8 ruthenium(0) complexes and their subsequent catalytic behaviourElectronic supplementary information (ESI) available: NMR characterisation, catalytic studies, and XYZ coordinates determined for optimised structures. See http://www.rsc.org/suppdata/dt/b4/b410912k/ (pp. 3616-3628) Dunne, John P.; Blazina, Damir; Aiken, Stuart; Carteret, Hilary A.; Duckett, Simon B.; Jones, Jonathan. A.; Poli, Rinaldo; Whitwood, Adrian C.
• Cp*Rh complexes with pyridyloxazolines: synthesis, fluxionality and applications as asymmetric catalysts for Diels–Alder reactions (pp. 3629-3634) Davies, David L.; Fawcett, John; Garratt, Shaun A.; Russell, David R.
• Water-soluble ruthenium(ii) catalysts [RuCl2(η6-arene){P(CH2OH)3}] for isomerization of allylic alcohols and alkyne hydrationElectronic supplementary information (ESI) available: Table S1: Isomerization of allylic alcohols catalyzed by the neutral complex [RuCl2(η6-C6Me6){P(CH2OH)3}] 2c under biphasic water/n-heptane conditions. See http://www.rsc.org/suppdata/dt/b4/b411177j/ (pp. 3635-3641) Cadierno, Victorio; Crochet, Pascale; García-Garrido, Sergio E.; Gimeno, José
• Photolytic and thermal properties of a new series of intramolecular bridged alkyl cobaloxime complexes (pp. 3642-3646) Yao, Kaian; Zhang, Xin; Mei, Yuhua; Chen, Huilan
• Phenolate and phenoxyl radical complexes of Co(ii) and Co(iii)Electronic supplementary information (ESI) available: Figs. SI1–SI4 and Table SI1. See http://www.rsc.org/suppdata/dt/b4/b410934a/ (pp. 3647-3653) Benisvy, Laurent; Bill, Eckhard; Blake, Alexander J.; Collison, David; Davies, E. Stephen; Garner, C. David; Guindy, Christina I.; McInnes, Eric J. L.; McArdle, Graeme; McMaster, Jonathan; Wilson, Claire; Wolowska, Joanna
• Synthesis, characterization, and stereochemistry of S-bridged CoIIIMCoIII (M = PdII, PtII) trinuclear complexes containing two non-bridging thiolato groups: building blocks for the construction of chiral heterometallic aggregatesElectronic supplementary information (ESI) available: Table S1: Absorption and CD spectral data of complexes of ΛΛ-[1]2+, ΛΛ-[2a]2+, ΛΛ-[2b]2+, and ΛΛΛΛ-[3]6+ in H2O. See http://www.rsc.org/suppdata/dt/b4/b409614b/ (pp. 3654-3661) Chikamoto, Yu; Hirotsu, Masakazu; Yamaguchi, Tadashi; Yoshimura, Takashi; Konno, Takumi
• Pseudo-rotation mechanism for fast olefin exchange and substitution processes at orthometalated C,N-complexes of platinum(ii)Electronic supplementary information (ESI) available: Observed rate constants for all reactions studied and carbon-13 NMR data for the complexes studied. See http://www.rsc.org/suppdata/dt/b4/b409887k/ (pp. 3662-3668) OttoPresent address: SASOL Technology R&D, P.O. Box 1, Sasolburg, South Africa, Stefanus; Samuleev, Pavel V.; Polyakov, Vladimir A.; Ryabov, Alexander D.; Elding, Lars I.
• Multinuclear platinum(ii)–amine complexes containing bis(aminopropyl)dicarba-closo-dodecaborane(12) ligands (pp. 3669-3677) Woodhouse, Susan L.; Rendina, Louis M.
• Aluminium alkyl and aryloxide complexes of pyrazine and bipyridines: synthesis and structureElectronic supplementary information (ESI) available: Elemental analysis and IR spectroscopy data; ab initio calculated structures and structural parameters of AlMe3(py) and (tBu)2Al(OPh)(py). See http://www.rsc.org/suppdata/dt/b4/b410662h/ (pp. 3689-3694) Ogrin, Doug; van Poppel, Laura H.; Bott, Simon G.; Barron, Andrew R.
• Unprecedented double nucleophilic addition of a hydride at a central carbon of an η3-allyl ligand (pp. 3695-3698) Minato, Makoto; Sekimizu, Ryoko; Uchida, Daisuke; Ito, Takashi
• Cyclometallated Pd(ii) azido complexes containing 6-phenyl-2,2′-bipyridyl or 2-phenylpyridyl derivatives: synthesis and reactivity toward organic isocyanides and isothiocyanatesElectronic supplementary information (ESI) available: Spectroscopic data. See http://www.rsc.org/suppdata/dt/b4/b411432a/ (pp. 3699-3708) Kim, Yong-Joo; Chang, Xiaohong; Han, Jin-Taek; Lim, Mi S.; Lee, Soon W.
• Oxidative addition of silanes R3SiH to the unsaturated cluster [Os3(μ-H){μ3-Ph2PCH2PPh(C6H4)}(CO)8]: Evidence for reversible silane formation in the dynamic behaviour of [Os3(μ-H)(SiR3)(CO)9(μ-dppm)] (pp. 3709-3714) Deeming, Antony J.; Hassan, Md. Manjur; Kabir, Shariff E.; Nordlander, Ebbe; Tocher, Derek A.
• Macrocyclic ligand design. Structure–function relationships involving the interaction of pyridinyl-containing, oxygen–nitrogen donor macrocycles with selected transition and post transition metal ions on progressive N-benzylation of their secondary aminesElectronic supplementary information (ESI) available: Table S1 (coordinated anion and other geometries [M(2)(NO3)2] (M = Co, Zn, Cd, Ni)) and Table S2 (ligand conformational descriptors); Fig. S1 (calculated geometry of the lowest found minimum structure of [Ag(4)]+) and Fig. S2 (calculated geometry of the minor disordered component of [Ag(4)]+. See http://www.rsc.org/suppdata/dt/b4/b412437e/ (pp. 3715-3726) Price, Jason R.; Fainerman-Melnikova, Marina; Fenton, Ronald R.; Gloe, Karsten; Lindoy, Leonard F.; Rambusch, Torsten; Skelton, Brian W.; Turner, Peter; White, Allan H.; Wichmann, Kathrin
• High-frequency EPR study of reduced diruthenium and dirhenium polypyridine complexes based on the 1,2,4,5-tetrazine radical bridge (pp. 3727-3731) Sarkar, Biprajit; Frantz, Stéphanie; Kaim, Wolfgang; Duboc, Carole
• Syntheses, structures and antimicrobial activities of water-soluble silver(i)–oxygen bonding complexes with chiral and racemic camphanic acid (Hca) ligands (pp. 3732-3740) Kasuga, Noriko Chikaraishi; Sugie, Akiyoshi; Nomiya, Kenji
• Effect of the tether on the Mg(ii), Ca(ii), Cu(ii) and Fe(iii) stability constants and pM values of chelating agents related to EDDHAElectronic supplementary information (ESI) available: Figs. 1S–4S and Tables 1S–5S. See http://www.rsc.org/suppdata/dt/b4/b408730e/ (pp. 3741-3747) Sierra, Miguel A.; Gómez-Gallego, Mar; Alcázar, Roberto; Lucena, Juan J.; Yunta, Felipe; García-Marco, Sonia
• Synthesis and luminescence studies of mono- and C3-symmetric, tris(ligand) complexes of Sm(iii), Y(iii) and Eu(iii) with sulfur-bridged binaphtholate ligands (pp. 3748-3755) Natrajan, Louise S.; Blake, Alexander J.; Wilson, Claire; Weinstein, Julia A.; Arnold, Polly L.
• Dinuclear N-heterocyclic carbene complexes of silver(i), derived from imidazolium-linked cyclophanes (pp. 3756-3764) Baker, Murray V.; Brown, David H.; Haque, Rosenani A.; Skelton, Brian W.; White, Allan H.
• Experimental investigations and ab initio studies of selenium(ii) dialkanethiolates, Se(SR)2 (pp. 3765-3771) Fleischer, Holger; Glang, Stefan; Schollmeyer, Dieter; Mitzel, Norbert W.; Bühl, Michael
• A new bis(3-hydroxy-4-pyridinone)-IDA derivative as a potential therapeutic chelating agent. Synthesis, metal-complexation and biological assays (pp. 3772-3781) Amélia Santos, M.; Gama, Sofia; Gano, Lurdes; Cantinho, Guilhermina; Farkas, Etelka
• 1,3,5-Triazine-based tricopper(ii) complexes: structure and magnetic properties of threefold-symmetric building blocksElectronic supplementary information (ESI) available: Figs. S1 and S2: EPR spectrum of 1 and 2 in frozen MeOH solution at 130 K, respectively. See http://www.rsc.org/suppdata/dt/b4/b407598f/ (pp. 3782-3787) Demeshko, Serhiy; Leibeling, Guido; Dechert, Sebastian; Meyer, Franc
• Roles of a tetrahydroborate ligand in a facile route to ruthenium(ii) ethyl hydride complexes, and a kinetic study of ethane reductive elimination (pp. 3788-3797) Duckett, Simon B.; Lowe (née Stott), J. Claire; Lowe, John P.; Mawby, Roger J.

Issue: 22

• Experimental and quantum chemical studies of structure and reaction mechanisms of dioxouranium(vi) complexes in solutionElectronic supplementary information (ESI) available: Perspective views, 17O NMR peaks, deconvolution of 31P NMR peaks and a structural scheme. See http://www.rsc.org/suppdata/dt/b4/b410005k/ (pp. 3799-3807) Vallet, Valérie; Szabó, Zoltán; Grenthe, Ingmar
• First transition-metal complexes of SP(NHBut)3Part 2 in the series “Organophosphorus(v) ligands for coordination and organometallic chemistry”. Part 1 is ref. 1. (pp. 3808-3809) Rufanov, Konstantin A.; Ziemer, Burkhard; Meisel, Manfred
• The effects of hydrofluoric acid addition on the hydrothermal synthesis of templated uranium sulfatesElectronic supplementary information (ESI) available: Powder X-ray diffraction patterns of USFO-1 and USO-26. See http://www.rsc.org/suppdata/dt/b4/b413062f/ (pp. 3810-3814) Doran, Michael B.; Cockbain, Ben E.; Norquist, Alexander J.; O'Hare, Dermot
• Reduced and excited states of the intermediates (α-diimine)(C5R5)Rh in hydride transfer catalysis schemes: EPR and resonance Raman spectroscopy, and comparative DFT calculations of Co, Rh and Ir analoguesElectronic supplementary information (ESI) available: Tables S1–S4. See http://www.rsc.org/suppdata/dt/b4/b411892h/ (pp. 3815-3821) Sieger, Monika; Kaim, Wolfgang; Stufkens, Derk J.; Snoeck, Theo L.; Stoll, Hermann; Záliš, Stanislav
• Sulfur, tin and gold derivatives of 1-(2′-pyridyl)-ortho-carborane, 1-R-2-X-1,2-C2B10H10 (R = 2′-pyridyl, X = SH, SnMe3 or AuPPh3) (pp. 3822-3828) Batsanov, Andrei S.; Fox, Mark A.; Hibbert, Thomas G.; Howard, Judith A. K.; Kivekäs, Raikko; LaromaineEnrolled in the UAB Ph. D. Program., Anna; Sillanpää, Reijo; Viñas, Clara; Wade, Kenneth
• Host–guest assembly of ligand systems for metal ion complexation. Synergistic solvent extraction of copper(ii) and silver(i) by 1,4,8,11-tetrabenzyl-1,4,8,11-tetraazacyclodecane in combination with carboxylic acidsElectronic supplementary information (ESI) available: Further experimental details for the (non-tracer) solvent extraction studies. See http://www.rsc.org/suppdata/dt/b4/b412255k/ (pp. 3829-3834) Gasperov, Vesna; Gloe, Karsten; Lindoy, Leonard F.; Mahinay, Myrna S.
• Synthesis and structure of Zn7(µ4-O)2(OAc)10(Pz)2 (OAc = acetate; Pz = pyrazine) (pp. 3840-3841) Waheed, Abdul; Jones, Richard A.; McCarty, Jeffrey; Yang, Xiaoping
• Dinuclear and mononuclear manganese(iv)-radical complexes and their catalytic catecholase activityElectronic supplementary information (ESI) available: Figs. 10 and 11. Analytical IR, NMR and mass spectrometric data for H2LCH3, H2LCl, H2LOCH3 and corresponding data for complexes 4–7. See http://www.rsc.org/suppdata/dt/b4/b410842f/ (pp. 3842-3853) Mukherjee, Soumen; Weyhermüller, Thomas; Bothe, Eberhard; Wieghardt, Karl; Chaudhuri, Phalguni
• Synthesis and characterization of mono- and binuclear platinum complexes containing terminal and bridging diynyldiphenylphosphine ligands (pp. 3854-3863) Forniés, Juan; García, Ana; Gil, Belén; Lalinde, Elena; Moreno, M. Teresa
• Di- and tri-alkylphosphine adducts of S-donor palladacycles as catalysts in the Suzuki coupling of aryl chlorides (pp. 3864-3868) Bedford, Robin B.; Cazin, Catherine S. J.; Hursthouse, Michael B.; Light, Mark E.; Scordia, Véronique J. M.
• Equilibrium, kinetic and HPLC study of the reactions between platinum(ii) complexes and DNA constituents in the presence and absence of glutathione (pp. 3869-3877) Bugarčić, Živadin D.; Soldatović, Tanja; Jelić, Ratomir; Algueró, Berta; Grandas, Anna
• An enormous vibrational motion: the gas-phase structure of dimethyl-bis(methoxyethynyl) germaniumElectronic supplementary information (ESI) available: final Cartesian coordinates of the optimised structures of the lowest-energy conformer of dimethyl-bis(methoxyethynyl) germanium obtained at the HF/6-311+G*, B3LYP/6-311+G* and the MP2/6-311+G* levels of theory. See http://www.rsc.org/suppdata/dt/b4/b412565g/ (pp. 3878-3882) Borisenko, Konstantin B.; Yezhov, Roman N.; Gruener, Sergej V.; Robertson, Heather E.; Rankin, David W. H.
• Transition metal complexes of the chelating phosphine borane ligand Ph2PCH2Ph2P·BH3 (pp. 3883-3892) Merle, Nicolas; Koicok-Köhn, Gabriele; Mahon, Mary F.; Frost, Christopher G.; Ruggerio, Giuseppe D.; Weller, Andrew S.; Willis, Michael C.
• Synthesis and structural characterization of two novel heterometallic clusters: [Rh4Pt2(CO)11(dppm)2] and [Ru2Rh2Pt2(CO)12(dppm)2]Electronic supplementary information (ESI) available: Fig. S1: 31P–{103Rh} HMQC NMR spectrum of 1. Tables 1–5: Crystallographic data, atomic coordinates, bond lengths, bond angles, anisotropic displacement parameters, hydrogen coordinates and isotropic displacement parameters, and hydrogen bonds for Rh4Pt2(CO)11(dppm)2 (1) Tables 6–10: Crystallographic data, atomic coordinates, bond lengths, bond angles, anisotropic displacement parameters, hydrogen coordinates and isotropic displacement parameters, and hydrogen bonds for Rh2Ru2Pt2(CO)12(dppm)2 (2). See http://www.rsc.org/suppdata/dt/b4/b410216a/ (pp. 3893-3899) Koshevoy, Igor O.; Grachova, Elena V.; Tunik, Sergey P.; Haukka, Matti; Pakkanen, Tapani A.; Heaton, Brian T.; Iggo, Jonathan A.; Podkorytov, Ivan S.
• Alkalicyamelurates, M3[C6N7O3]·xH2O, M = Li, Na, K, Rb, Cs: UV-luminescent and thermally very stable ionic tri-s-triazine derivativesTri-s-triazine derivatives. Part 2.1 (pp. 3900-3908) Horvath-Bordon, Elisabeta; Kroke, Edwin; Svoboda, Ingrid; Fueß, Hartmut; Riedel, Ralf; Neeraj, Sharma; Cheetham, Anthony K.
• Synthesis and characterization of half-sandwich N-heterocyclic carbene complexes of cobalt and rhodium (pp. 3909-3917) Fooladi, Erik; DalhusCurrent address: Institute of Medical Microbiology, Section for Molecular Microbiology, National Hospital, N-0027 Oslo, Norway., Bjørn; Tilset, Mats
• New types of the flexible self-assembled metal–organic coordination polymers constructed by aliphatic dicarboxylates and rigid bidentate nitrogen ligandsElectronic supplementary information (ESI) available: X-Ray powder diffraction patterns of complexes 1–4, corresponding simulated patterns, and those of dehydrated compounds 1, 3 and 4. See http://www.rsc.org/suppdata/dt/b4/b410235e/ (pp. 3918-3925) Mao, Hongyan; Zhang, Changzheng; Li, Gang; Zhang, Hongyun; Hou, Hongwei; Li, Linke; Wu, Qingan; Zhu, Yu; Wang, Enbo

Issue: 23

• Hydroalumination reactions on acetylenes and nitriles in the synthesis of carbaalanes and imidoalanes: an overviewDedicated to Professor Tobin J. Marks on the occasion of his 60th birthday. (pp. 3927-3937) Kumar, S. Shravan; Roesky, Herbert W.
• Ferromagnetic coupling and thermochromism in [Ni(rac-CTH)(µ1,1-N3)2Cu(N3)2], the first end-on azido-bridged bimetallic complex (pp. 3938-3940) Suárez-Varela, José; Maimoun, I. B.; Colacio, Enrique
• Arrested chloride abstraction from trans-RuCl2(DMeOPrPE)2 with TlPF6; formation of a 1-D coordination polymer having unusual octahedral coordination around thallium(i)Electronic Supplementary Information (ESI) available: 31P{1H} NMR spectra and crystallographic information. See http://www.rsc.org/suppdata/dt/b4/b415259j/ (pp. 3941-3942) Szymczak, Nathaniel K.; Han, Fusen; Tyler, David R.
• Assessment of intercomponent interaction in phenylene bridged dinuclear ruthenium(ii) and osmium(ii) polypyridyl complexesElectronic supplementary information (ESI) available: Fig. S1: 1H NMR spectra of Ru and RuRu. Fig. S2: Resonance Raman spectra of dRudRu, RuRu and OsOs. Fig. S3: Reductive and oxidative electrochemistry of Ru. Fig. S4: Frontier orbitals of RuRu. Table S1: 1H NMR spectra of L1 and L1 in dRudRu. Table S2: Selected bond distances. Table S3: Selected bond angles. Table S4: Calculated data for the frontier orbitals of RuRu. See http://www.rsc.org/suppdata/dt/b4/b409189b/ (pp. 3943-3949) Guckian, Adrian L.; Doering, Manfred; Ciesielski, Michael; Walter, Olaf; Hjelm, Johan; O'Boyle, Noel M.; Henry, William; Browne, Wesley R.; McGarvey, John J.; Vos, Johannes G.
• A cautionary warning on the use of electrochemical measurements to calculate comproportionation constants for mixed-valence compoundsElectronic supplementary information (ESI) available: Electrochemical data. See http://www.rsc.org/suppdata/dt/b4/b413980a/ (pp. 3950-3954) D'Alessandro, Deanna M.; Keene, F. Richard
• Solid-state spectroscopic properties and the geometry of binuclear rhodium(i) diisocyanoalkane complexesElectronic supplementary information (ESI) available: A discussion on the disorder treatment; tables of crystallographic information. See http://www.rsc.org/suppdata/dt/b4/b412942c/ (pp. 3955-3962) Gerlits, Oksana; Kovalevsky, Andrey Yu.; Coppens, Philip
• Titanium and niobium imido complexes stabilized by heteroscorpionate ligands (pp. 3963-3969) Otero, A.; Fernández-Baeza, J.; Antiñolo, A.; Tejeda, J.; Lara-Sánchez, A.; Sánchez-Barba, L.; Rodríguez, A. M.
• Mono- and binuclear cyclometallated palladium(ii) complexes containing bridging (N,O-) and terminal (N-) imidate ligands: Air stable, thermally robust and recyclable catalysts for cross-coupling processes (pp. 3970-3981) Fairlamb, Ian J. S.; Kapdi, Anant R.; Lee, Adam F.; Sánchez, Gregorio; López, Gregorio; Serrano, José Luis; García, Luis; Pérez, José; Pérez, Eduardo
• Reaction of [M(η3-allyl)(η2-amidinato)(CO)2(pyridine)] complexes (M = Mo, W) with bidentate ligands: nitrogen donor vs. phosphorus donorElectronic supplementary information (ESI) available: ORTEP drawings of complexes 2, 5 and 6 with the atom-numbering scheme and 2D-NMR spectra of complex 6. See http://www.rsc.org/suppdata/dt/b4/b410927a/ (pp. 3982-3990) Yamaguchi, Yoshitaka; Ogata, Kenichi; Kobayashi, Kimiko; Ito, Takashi
• Protonation and H/D exchange reactions promoted by a sulfur-rich osmium hydride complex: identification of a labile dihydrogen complexTransition metal complexes with sulfur ligands. Part 171.1 (pp. 3991-3996) Sellmann, Dieter; Prakash, Raju; Heinemann, Frank W.
• Mono-, di- and trinuclear 2,3,5,6-tetrakis(2-pyridyl)pyrazine (tppz)-containing copper(ii) complexes: syntheses, crystal structures and magnetic propertiesElectronic supplementary information (ESI) available: Fig. S1: Dinuclear entity in 1, [Cu(tppz)(NCO)2(H2O)], with copper–copper interaction indicated. Fig. S2: Association of tetranuclear units into chains in 2, [Cu2(tppz)Br4]. See http://www.rsc.org/suppdata/dt/b4/b412034p/ (pp. 3997-4005) Carranza, José; Sletten, Jorunn; Brennan, Conor; Lloret, Francesc; Cano, Joan; Julve, Miguel
• Preparation, electrochemical and spectral properties of N-methyl-pyridylethynyl nickel porphyrins (pp. 4006-4009) Lin, Ching-Yao; Chuang, Li-Chieh; Lin, Yu-Chin; Lin, Chia-Liang
• Gas phase oxidation of alkoxo ligands in bis(peroxo) [MO(O2)2(OR)]− and trisoxo [MO3(OR)]− anions (M = Cr, Mo, W) (pp. 4010-4016) Feyel, Sandra; Waters, Tom; O'Hair, Richard A. J.; Wedd, Anthony G.
• Tin(iv) halide complexes of AsPh3: The structures of trans-SnCl4(AsPh3)2 and SnBr4(AsPh3)·AsPh3Electronic supplementary information (ESI) available: SEM of the film deposited by AACVD using (1) as the precursor: (Fig. 6) showing the underlay with the larger crystallites superimposed, (Fig. 7) showing the particulate nature of the film and the film thickness; SEM showing ill-formed crystallites deposited on the surface of the layer of SnO2 (Fig. 8). See http://www.rsc.org/suppdata/dt/b4/b411342j/ (pp. 4017-4021) Mahon, Mary F.; Moldovan, Natalia L.; Molloy, Kieran C.; Muresan, Alexandra; Silaghi-Dumitrescu, Ioan; Silaghi-Dumitrescu, Luminita
• Synthesis, characterization, and electrochemical and electrochromic properties of sandwich dilutetium tetraphthalocyanine (pp. 4022-4029) Abdurrahmanoğlu, Şaziye; Özkaya, Ali Riza; Bulut, Mustafa; Bekaroğlu, Özer
• Reactivity of the bis(pentafluorophenyl)boranes ClB(C6F5)2 and [HB(C6F5)2]n towards late transition metal reagentsElectronic supplementary information (ESI) available: Crystal data for the monoclinic form of 3 and 8·3CHCl3; DFT parameters for (η5-C5H5)Fe(CO)2BX2 [X = C6F5, C6H5]. See http://www.rsc.org/suppdata/dt/b4/b414940h/ (pp. 4030-4037) Al-Fawaz, Amal; Aldridge, Simon; Coombs, Deborah L.; Dickinson, Anthony A.; Willock, David J.; Ooi, Li-ling; Light, Mark E.; Coles, Simon J.; Hursthouse, Michael B.
• Vibrational spectroscopic force field studies of dimethyl sulfoxide and hexakis(dimethyl sulfoxide)scandium(iii) iodide, and crystal and solution structure of the hexakis(dimethyl sulfoxide)scandium(iii) ionElectronic supplementary information (ESI) available: Description of the internal and symmetry coordinates of [Sc(OSMe2)6]3+, fundamental vibrations of (CH3)2SO and (CD3)2SO molecules in 0.6 M CCl4 solution, intermolecular interactions from dimethyl sulfoxide crystal structure, EXAFS data for [Sc(OSMe2)6]3+ in dimethyl sulfoxide solution with WinXAS fitted model functions and separate scattering contributions and Fourier transforms with magnitudes and imaginary parts, Raman and IR spectra of deuterated dimethyl sulfoxide and of [Sc(OS(CD3)2)6]I3. See http://www.rsc.org/suppdata/dt/b4/b413486a/ (pp. 4038-4049) Skripkin, Mikhail Yu.; Lindqvist-Reis, Patric; Abbasi, Alireza; Mink, János; Persson, Ingmar; Sandström, Magnus
• Chiral metal architectures in aminopyridinato complexes of zirconiumElectronic supplementary information (ESI) available: Details of NOESY and SPT-SIR NMR spectra, rotatable structure files for X-ray and DFT output.. See http://www.rsc.org/suppdata/dt/b4/b413023e/ (pp. 4050-4058) Crust, Edward J.; Clarke, Adam J.; Deeth, Robert J.; Morton, Colin; Scott, Peter
• Formation and reactions of metal–metal bonded heterobimetallic (C5H4PR2)-bridged (Zr–Ir) and (Zr–Rh) complexes: evidence for the participation of metal hydride intermediates (pp. 4059-4063) Cornelißen, Carsten; Erker, Gerhard; Kehr, Gerald; FröhlichX-Ray structural analysis., Roland
• Reactivity of aqua coordinated monoporphyrinate lanthanide complexes: synthetic, structural and photoluminescent studies of lanthanide porphyrinate dimers (pp. 4064-4073) He, Hongshan; Zhu, Xunjin; Hou, Anxin; Guo, Jianping; Wong, Wai-Kwok; Wong, Wai-Yeung; Li, King-Fai; Cheah, Kok-Wai
• Complexes of a dianionic bis(diphosphinomethanide) with lithium, sodium, potassium and zirconium. Effect of substitution on the Schlenk dimerisation of vinylidene phosphines (pp. 4074-4078) Izod, Keith; McFarlane, William; Tyson, Brent V.; Clegg, William; Harrington, Ross W.

Issue: 24

• Bio-mimicking galactose oxidase and hemocyanin, two dioxygen-processing copper proteins (pp. 4079-4088) Gamez, Patrick; Koval, Iryna A.; Reedijk, Jan
• Synthesis of the new, weakly coordinating anions [RB(C6F5)3]− (R = CH2Me, CHMe2, CH2CMe3); utilization of [HNMe2Ph][Me3CCH2B(C6F5)3] to activate zirconocene catalysts for propylene polymerizationElectronic supplementary information (ESI) available: 1H, 19F and 11B NMR data, electrospray MS data for all new compounds. See http://www.rsc.org/suppdata/dt/b4/b410941d/ (pp. 4089-4091) Bavarian, Neda; Baird, Michael C.
• Nucleophilic substitution on a Ru-coordinated Cp ring by a carborane anion (pp. 4092-4093) Basato, Marino; Biffis, Andrea; Tubaro, Cristina; Graiff, Claudia; Tiripicchio, Antonio
• Semi-vacant Wells–Dawson anions. Synthesis of tri-tungsten-vacant derivatives and crystallographic studies of [αββα-(CuIIOH2)2(CuII)2(AsW15(OH2)3(OH)O52)2]12−Electronic supplementary information (ESI) available: Thermal ellipsoid plot of 2 (Fig. 1S), W(vi)-based reduction potentials for 1, 1Zn and 1Cu (Table S1). See http://www.rsc.org/suppdata/dt/b4/b414831b/ (pp. 4094-4095) Mbomekalle, Israel Martyr; Keita, Bineta; Nadjo, Louis; Hardcastle, Kenneth I.; Hill, Craig L.; Anderson, Travis M.
• Statistical mechanical approach to competitive binding of metal ions to multi-center receptors (pp. 4096-4105) Borkovec, Michal; Hamáček, Josef; Piguet, Claude
• C–F or C–H bond activation and C–C coupling reactions of fluorinated pyridines at rhodium: synthesis, structure and reactivity of a variety of tetrafluoropyridyl complexesDedicated to Professor Gerd-Volker Röschenthaler on the occasion of his 60th birthday. (pp. 4106-4119) Noveski, Daniel; Braun, Thomas; Neumann, Beate; Stammler, Anja; Stammler, Hans-Georg
• Bulk material vs. single crystal: powder diffraction to the rescue (pp. 4120-4123) Dikarev, Evgeny V.; Chernyshev, Vladimir V.; Shpanchenko, Roman V.; Filatov, Alexander S.; Petrukhina, Marina A.
• Diastereoisomeric dinuclear ruthenium complexes of 2,5-di(2-pyridyl)thiazolo[5,4-d]thiazole (pp. 4124-4129) Zampese, Jennifer A.; Keene, F. Richard; Steel, Peter J.
• Ruthenium bipyridyl compounds with two terminal alkynyl ligands (pp. 4130-4138) Adams, Christopher J.; Bowen, Lucy E.; Humphrey, Mark G.; Morrall, Joseph P. L.; Samoc, Marek; Yellowlees, Lesley J.
• Synthesis and crystal structure of tetra- and hexanuclear uranium(iv) complexes with hexadentate compartmental Schiff-base ligands (pp. 4139-4145) Salmon, Lionel; Thuéry, Pierre; Ephritikhine, Michel
• A stepwise degradation of sterically hindered CpCo-cyclobutadiene complexes (pp. 4146-4151) Schaefer, Carsten; Gleiter, Rolf; Rominger, Frank
• Interactions of Ni(ii) and Cu(ii) ions with the hydrolysis products of the C-terminal -ESHH- motif of histone H2A model peptides. Association of the stability of the complexes formed with the cleavage of the -E–S- bond (pp. 4152-4160) Mylonas, Marios; Plakatouras, John C.; Hadjiliadis, Nick
• End-to-end single cyanato and thiocyanato bridged Cu(ii) polymers with a new tridentate Schiff base ligand: Crystal structure and magnetic properties (pp. 4161-4167) Talukder, Pritha; Datta, Amitabha; Mitra, Samiran; Rosair, Georgina; El Fallah, M. Salah; Ribas, Joan
• Proton induced P–H and Mo–H bond activation at the phosphide bridged dimolybdenum complexes [Mo2Cp2(µ-H)(µ-PHR)(CO)4] (R = Cy, 2,4,6-C6H2R′3; R′ = H, Me, tBu) (pp. 4168-4179) Alvarez, Celedonio M.; Alvarez, M. Angeles; García-Vivó, Daniel; García, M. Esther; Ruiz, Miguel A.; Sáez, David; Falvello, Larry R.; Soler, Tatiana; Herson, Patrick
• Synthetic analogue approach for the functional domains of copper(ii) bleomycins and its DNA cleavage activityElectronic supplementary information (ESI) available: Variable temperature magnetic susceptibility data (Table S1), χMT vs. T plot and unit cell packing diagram of 1 (Figs. S1, S2). See http://www.rsc.org/suppdata/dt/b4/b414639e/ (pp. 4180-4184) Dhar, Shanta; Nethaji, Munirathinam; Chakravarty, Akhil R.
• Investigating the effect of hydrogen bonding environments in amide cleavage reactions at zinc(ii) complexes with intramolecular amide oxygen co-ordination (pp. 4185-4192) Rivas, Juan C. Mareque; Salvagni, Emiliano; Parsons, Simon
• Synthesis and structures of β-diketiminatotin(ii) halides, an amide and of Sn(E)[{N(R)C(Ph)}2CH](NR2) (E = S or Se, R = SiMe3) (pp. 4193-4201) Hitchcock, Peter B.; Hu, Jin; Lappert, Michael F.; Severn, John R.
• Water-soluble hydroxyalkylated phosphines: examples of their differing behaviour toward ruthenium and rhodium (pp. 4202-4208) Higham, Lee J.; Whittlesey, Michael K.; Wood, Paul T.